Tetrakis(dimethylamino)ethylene (TDAE)-Pd promoted reductive homo-coupling of aryl halides

Manabu Kuroboshi, Yoko Waki, Hideo Tanaka

Research output: Contribution to journalArticle

22 Citations (Scopus)

Abstract

A combination of tetrakis(dimethylamino)ethylene (TDAE) and palladium catalysts promoted reductive homo-coupling of aryl halides efficiently to afford the corresponding biaryls in good to quantitative yields. TDAE acted as a very mild reductant, and easily reducible functional groups, such as a nitro formyl, ester, or nitrile group, remained unchanged.

Original languageEnglish
Pages (from-to)637-639
Number of pages3
JournalSynlett
Issue number4
Publication statusPublished - 2002

Fingerprint

Nitriles
Reducing Agents
Palladium
Functional groups
Esters
Catalysts
tetrakis(dimethylamino)ethylene

Keywords

  • Aryl halides
  • Biaryls
  • Organic reductant
  • Palladium
  • Reductive homo-coupling

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Tetrakis(dimethylamino)ethylene (TDAE)-Pd promoted reductive homo-coupling of aryl halides. / Kuroboshi, Manabu; Waki, Yoko; Tanaka, Hideo.

In: Synlett, No. 4, 2002, p. 637-639.

Research output: Contribution to journalArticle

@article{29df00c2b9864db2a1999adaf647eb39,
title = "Tetrakis(dimethylamino)ethylene (TDAE)-Pd promoted reductive homo-coupling of aryl halides",
abstract = "A combination of tetrakis(dimethylamino)ethylene (TDAE) and palladium catalysts promoted reductive homo-coupling of aryl halides efficiently to afford the corresponding biaryls in good to quantitative yields. TDAE acted as a very mild reductant, and easily reducible functional groups, such as a nitro formyl, ester, or nitrile group, remained unchanged.",
keywords = "Aryl halides, Biaryls, Organic reductant, Palladium, Reductive homo-coupling",
author = "Manabu Kuroboshi and Yoko Waki and Hideo Tanaka",
year = "2002",
language = "English",
pages = "637--639",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "4",

}

TY - JOUR

T1 - Tetrakis(dimethylamino)ethylene (TDAE)-Pd promoted reductive homo-coupling of aryl halides

AU - Kuroboshi, Manabu

AU - Waki, Yoko

AU - Tanaka, Hideo

PY - 2002

Y1 - 2002

N2 - A combination of tetrakis(dimethylamino)ethylene (TDAE) and palladium catalysts promoted reductive homo-coupling of aryl halides efficiently to afford the corresponding biaryls in good to quantitative yields. TDAE acted as a very mild reductant, and easily reducible functional groups, such as a nitro formyl, ester, or nitrile group, remained unchanged.

AB - A combination of tetrakis(dimethylamino)ethylene (TDAE) and palladium catalysts promoted reductive homo-coupling of aryl halides efficiently to afford the corresponding biaryls in good to quantitative yields. TDAE acted as a very mild reductant, and easily reducible functional groups, such as a nitro formyl, ester, or nitrile group, remained unchanged.

KW - Aryl halides

KW - Biaryls

KW - Organic reductant

KW - Palladium

KW - Reductive homo-coupling

UR - http://www.scopus.com/inward/record.url?scp=0036219579&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0036219579&partnerID=8YFLogxK

M3 - Article

SP - 637

EP - 639

JO - Synlett

JF - Synlett

SN - 0936-5214

IS - 4

ER -