Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source: Alkenylation of aldehydes using an Ni/Cr/TDAE redox system

Manabu Kuroboshi, Muneaki Tanaka, Suguru Kishimoto, Kentaro Goto, Misato Mochizuki, Hideo Tanaka

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

Tetrakis(dimethylamino)ethylene (TDAE) was found to be a potent organic electron source which could promote alkenylation of several kinds of aldehydes in the presence of a catalytic amount of NiBr2 and CrCl3.

Original languageEnglish
Pages (from-to)81-84
Number of pages4
JournalTetrahedron Letters
Volume41
Issue number1
DOIs
Publication statusPublished - Jan 1 2000

Fingerprint

Alkenylation
Electron sources
Aldehydes
Oxidation-Reduction
Electrons
tetrakis(dimethylamino)ethylene

Keywords

  • Aldehydes
  • Alkenylation
  • Enamines
  • Reduction

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source : Alkenylation of aldehydes using an Ni/Cr/TDAE redox system. / Kuroboshi, Manabu; Tanaka, Muneaki; Kishimoto, Suguru; Goto, Kentaro; Mochizuki, Misato; Tanaka, Hideo.

In: Tetrahedron Letters, Vol. 41, No. 1, 01.01.2000, p. 81-84.

Research output: Contribution to journalArticle

Kuroboshi, Manabu ; Tanaka, Muneaki ; Kishimoto, Suguru ; Goto, Kentaro ; Mochizuki, Misato ; Tanaka, Hideo. / Tetrakis(dimethylamino)ethylene (TDAE) as a potent organic electron source : Alkenylation of aldehydes using an Ni/Cr/TDAE redox system. In: Tetrahedron Letters. 2000 ; Vol. 41, No. 1. pp. 81-84.
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