TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes

Atsunori Mori, Akinori Fujita, Kazutaka Ikegashira, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The fluoride reagents, TBAH2F3 and TBAHF2 (TBA: tetrabutylammonium), are found to catalyze the reactions of hexamethyldisilane with 1,3-dienes, aliphatic aldehydes, and aromatic aldehydes to give 1,4-disilyl-2-butenes, α-silyl alcohols and pinacols, respectively. Using an equimolar amount of TBAHF2 and disilanes, reduction of carbonyl compounds occurs in place of the silyl group addition.

Original languageEnglish
Pages (from-to)693-694
Number of pages2
JournalSynlett
Volume1997
Issue number6
DOIs
Publication statusPublished - Jan 1 1997
Externally publishedYes

ASJC Scopus subject areas

  • Organic Chemistry

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