TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes

Atsunori Mori, Akinori Fujita, Kazutaka Ikegashira, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The fluoride reagents, TBAH2F3 and TBAHF2 (TBA: tetrabutylammonium), are found to catalyze the reactions of hexamethyldisilane with 1,3-dienes, aliphatic aldehydes, and aromatic aldehydes to give 1,4-disilyl-2-butenes, α-silyl alcohols and pinacols, respectively. Using an equimolar amount of TBAHF2 and disilanes, reduction of carbonyl compounds occurs in place of the silyl group addition.

Original languageEnglish
Pages (from-to)693-694
Number of pages2
JournalSynlett
Volume1997
Issue number6
Publication statusPublished - 1997
Externally publishedYes

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Aldehydes
Carbonyl compounds
Fluorides
Alcohols
2-butene
hexamethyldisilane
tetrabutylammonium

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Mori, A., Fujita, A., Ikegashira, K., Nishihara, Y., & Hiyama, T. (1997). TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes. Synlett, 1997(6), 693-694.

TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes. / Mori, Atsunori; Fujita, Akinori; Ikegashira, Kazutaka; Nishihara, Yasushi; Hiyama, Tamejiro.

In: Synlett, Vol. 1997, No. 6, 1997, p. 693-694.

Research output: Contribution to journalArticle

Mori, A, Fujita, A, Ikegashira, K, Nishihara, Y & Hiyama, T 1997, 'TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes', Synlett, vol. 1997, no. 6, pp. 693-694.
Mori A, Fujita A, Ikegashira K, Nishihara Y, Hiyama T. TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes. Synlett. 1997;1997(6):693-694.
Mori, Atsunori ; Fujita, Akinori ; Ikegashira, Kazutaka ; Nishihara, Yasushi ; Hiyama, Tamejiro. / TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes. In: Synlett. 1997 ; Vol. 1997, No. 6. pp. 693-694.
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