Taxpropellane: A novel taxane with an unprecedented polycyclic skeleton from the needles of Taxus canadensis

Man Li Zhang; Mei Dong; Chang Hong Huo; Li Geng Li; Françoise Sauriol; Qing Wen Shi; Yu Cheng Gu; Hidefumi Makabe; Hiromasa Kiyota

doi:10.1002/ejoc.200800587

Taxpropellane: A novel taxane with an unprecedented polycyclic skeleton from the needles of Taxus canadensis

Man Li Zhang, Mei Dong, Chang Hong Huo, Li Geng Li, Françoise Sauriol, Qing Wen Shi, Yu Cheng Gu, Hidefumi Makabe, Hiromasa Kiyota

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Taxpropellane, the first example of a taxane with an unprecedented 6/5/5/6/4/5-membered ring hexacyclic skeleton ([3.3.2]propellane), was isolated from the needles of Taxus canadensis. This compound would be derived from a normal 6/8/6 taxane by a [2+2] cycloaddition reaction between the 3,4- and 11,12-double bonds.

Original language	English
Pages (from-to)	5414-5417
Number of pages	4
Journal	European Journal of Organic Chemistry
Issue number	32
DOIs	https://doi.org/10.1002/ejoc.200800587
Publication status	Published - Nov 1 2008
Externally published	Yes

Keywords

Fused-ring systems
Propellanes
Structure elucidation
Terpenoids

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1002/ejoc.200800587

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Taxpropellane : A novel taxane with an unprecedented polycyclic skeleton from the needles of Taxus canadensis. / Zhang, Man Li; Dong, Mei; Huo, Chang Hong; Li, Li Geng; Sauriol, Françoise; Shi, Qing Wen; Gu, Yu Cheng; Makabe, Hidefumi; Kiyota, Hiromasa.

In: European Journal of Organic Chemistry, No. 32, 01.11.2008, p. 5414-5417.

Research output: Contribution to journal › Article › peer-review

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