Systematic analysis of 3d core photoemission spectra in rare earth oxides

A. Kotani, T. Ikeda, K. Okada, H. Ogasawara

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Systematic analysis is carried out for 3d core photoemission spectra of rare earth oxides R2O3 and RO2 for various rare earth elements R with the use of the impurity Anderson model. We estimate the values of the charge transfer energy, the hybridization strength, etc, and discuss the mechanism of the splitting of these photoemission spectra. We also point out the reason why the RO2 structure is stable only for R = Ce1, Pr and Tb.

Original languageEnglish
Pages (from-to)229-236
Number of pages8
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume51
Issue numberC
DOIs
Publication statusPublished - 1990
Externally publishedYes

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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