Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment

Isao Kadota, Choul Hong Park, Kumi Sato, Yoshinori Yamamoto

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

The AB ring segment of gambierol (1) was synthesized from 2-deoxy-D-ribose in 23 steps. The key steps were Brown's asymmetric allylboration of the aldehyde 5 and the intramolecular hetero-Michael reaction of 7.

Original languageEnglish
Pages (from-to)6195-6197
Number of pages3
JournalTetrahedron Letters
Volume42
Issue number35
DOIs
Publication statusPublished - Aug 27 2001
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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