Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment

Isao Kadota; Choul Hong Park; Kumi Sato; Yoshinori Yamamoto

doi:10.1016/S0040-4039(01)01204-7

Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment

Isao Kadota, Choul Hong Park, Kumi Sato, Yoshinori Yamamoto

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The AB ring segment of gambierol (1) was synthesized from 2-deoxy-D-ribose in 23 steps. The key steps were Brown's asymmetric allylboration of the aldehyde 5 and the intramolecular hetero-Michael reaction of 7.

Original language	English
Pages (from-to)	6195-6197
Number of pages	3
Journal	Tetrahedron Letters
Volume	42
Issue number	35
DOIs	https://doi.org/10.1016/S0040-4039(01)01204-7
Publication status	Published - Aug 27 2001
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)01204-7

Cite this

@article{8bdb176cc1df45dc85bd256c98772ac7,

title = "Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment",

abstract = "The AB ring segment of gambierol (1) was synthesized from 2-deoxy-D-ribose in 23 steps. The key steps were Brown's asymmetric allylboration of the aldehyde 5 and the intramolecular hetero-Michael reaction of 7.",

author = "Isao Kadota and Park, {Choul Hong} and Kumi Sato and Yoshinori Yamamoto",

note = "Funding Information: This work was financially supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Science and Culture of Japan.",

year = "2001",

month = aug,

day = "27",

doi = "10.1016/S0040-4039(01)01204-7",

language = "English",

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journal = "Tetrahedron Letters",

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T1 - Synthetic studies towards gambierol. Part 1

T2 - Synthesis of the AB ring segment

AU - Kadota, Isao

AU - Park, Choul Hong

AU - Sato, Kumi

AU - Yamamoto, Yoshinori

N1 - Funding Information: This work was financially supported by the Grant-in-Aid for Scientific Research from the Ministry of Education, Science and Culture of Japan.

PY - 2001/8/27

Y1 - 2001/8/27

N2 - The AB ring segment of gambierol (1) was synthesized from 2-deoxy-D-ribose in 23 steps. The key steps were Brown's asymmetric allylboration of the aldehyde 5 and the intramolecular hetero-Michael reaction of 7.

AB - The AB ring segment of gambierol (1) was synthesized from 2-deoxy-D-ribose in 23 steps. The key steps were Brown's asymmetric allylboration of the aldehyde 5 and the intramolecular hetero-Michael reaction of 7.

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U2 - 10.1016/S0040-4039(01)01204-7

DO - 10.1016/S0040-4039(01)01204-7

M3 - Article

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SN - 0040-4039

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SP - 6195

EP - 6197

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 35

ER -

Synthetic studies towards gambierol. Part 1: Synthesis of the AB ring segment

Abstract

ASJC Scopus subject areas

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