Synthesis, structures, and properties of plumboles

Masaichi Saito, Masafumi Sakaguchi, Tomoyuki Tajima, Kazuya Ishimura, Shigeru Nagase

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Reactions of 1,4-dilithio-1,2,3,4-tetraphenyl-1,3-butadiene with dichlorodiphenylplumbane gave hexaphenylplumbole 1 and spirobiplumbole 2. These structures were determined by X-ray diffraction analysis. Electronic structures of 1 and 2 were discussed by the aid of NMR analysis and theoretical calculations. The compounds 1 and 2 were found to be the first fluorescent organolead compounds.

Original languageEnglish
Pages (from-to)1068-1076
Number of pages9
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume185
Issue number5-6
DOIs
Publication statusPublished - May 2010
Externally publishedYes

Fingerprint

X-Ray Diffraction
X ray diffraction analysis
Electronic structure
Nuclear magnetic resonance
1,3-butadiene

Keywords

  • Fluorescence
  • Hexaphenylplumbole
  • Spirobiplumbole
  • Theoretical calculation
  • X-ray diffraction analysis

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Biochemistry

Cite this

Synthesis, structures, and properties of plumboles. / Saito, Masaichi; Sakaguchi, Masafumi; Tajima, Tomoyuki; Ishimura, Kazuya; Nagase, Shigeru.

In: Phosphorus, Sulfur and Silicon and the Related Elements, Vol. 185, No. 5-6, 05.2010, p. 1068-1076.

Research output: Contribution to journalArticle

Saito, Masaichi ; Sakaguchi, Masafumi ; Tajima, Tomoyuki ; Ishimura, Kazuya ; Nagase, Shigeru. / Synthesis, structures, and properties of plumboles. In: Phosphorus, Sulfur and Silicon and the Related Elements. 2010 ; Vol. 185, No. 5-6. pp. 1068-1076.
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