Synthesis, structures, and properties of plumboles

Masaichi Saito; Masafumi Sakaguchi; Tomoyuki Tajima; Kazuya Ishimura; Shigeru Nagase

doi:10.1080/10426501003773399

Synthesis, structures, and properties of plumboles

Masaichi Saito, Masafumi Sakaguchi, Tomoyuki Tajima, Kazuya Ishimura, Shigeru Nagase

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Reactions of 1,4-dilithio-1,2,3,4-tetraphenyl-1,3-butadiene with dichlorodiphenylplumbane gave hexaphenylplumbole 1 and spirobiplumbole 2. These structures were determined by X-ray diffraction analysis. Electronic structures of 1 and 2 were discussed by the aid of NMR analysis and theoretical calculations. The compounds 1 and 2 were found to be the first fluorescent organolead compounds.

Original language	English
Pages (from-to)	1068-1076
Number of pages	9
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	185
Issue number	5-6
DOIs	https://doi.org/10.1080/10426501003773399
Publication status	Published - May 2010
Externally published	Yes

Keywords

Fluorescence
Hexaphenylplumbole
Spirobiplumbole
Theoretical calculation
X-ray diffraction analysis

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426501003773399

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title = "Synthesis, structures, and properties of plumboles",

abstract = "Reactions of 1,4-dilithio-1,2,3,4-tetraphenyl-1,3-butadiene with dichlorodiphenylplumbane gave hexaphenylplumbole 1 and spirobiplumbole 2. These structures were determined by X-ray diffraction analysis. Electronic structures of 1 and 2 were discussed by the aid of NMR analysis and theoretical calculations. The compounds 1 and 2 were found to be the first fluorescent organolead compounds.",

keywords = "Fluorescence, Hexaphenylplumbole, Spirobiplumbole, Theoretical calculation, X-ray diffraction analysis",

author = "Masaichi Saito and Masafumi Sakaguchi and Tomoyuki Tajima and Kazuya Ishimura and Shigeru Nagase",

note = "Funding Information: Received 2 December 2008; accepted 15 December 2008. Dedicated to Professor Naomichi Furukawa on the occasion of his 70th birthday. This work was partially supported by Grant-in-Aids for Scientific Research (No. 20038010 for M.S. and No. 18066017 for S.N.) in Priority Areas “Molecular Theory for Real Systems” and the Nanotechnology Support Project from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. M. Saito acknowledges a research grant from Toray Science Foundation. Address correspondence to Masaichi Saito, Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama 338-8570, Japan. E-mail: masaichi@chem.saitama-u.ac.jp",

year = "2010",

month = may,

doi = "10.1080/10426501003773399",

language = "English",

volume = "185",

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T1 - Synthesis, structures, and properties of plumboles

AU - Saito, Masaichi

AU - Sakaguchi, Masafumi

AU - Tajima, Tomoyuki

AU - Ishimura, Kazuya

AU - Nagase, Shigeru

N1 - Funding Information: Received 2 December 2008; accepted 15 December 2008. Dedicated to Professor Naomichi Furukawa on the occasion of his 70th birthday. This work was partially supported by Grant-in-Aids for Scientific Research (No. 20038010 for M.S. and No. 18066017 for S.N.) in Priority Areas “Molecular Theory for Real Systems” and the Nanotechnology Support Project from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. M. Saito acknowledges a research grant from Toray Science Foundation. Address correspondence to Masaichi Saito, Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo, Sakura-ku, Saitama-city, Saitama 338-8570, Japan. E-mail: masaichi@chem.saitama-u.ac.jp

PY - 2010/5

Y1 - 2010/5

N2 - Reactions of 1,4-dilithio-1,2,3,4-tetraphenyl-1,3-butadiene with dichlorodiphenylplumbane gave hexaphenylplumbole 1 and spirobiplumbole 2. These structures were determined by X-ray diffraction analysis. Electronic structures of 1 and 2 were discussed by the aid of NMR analysis and theoretical calculations. The compounds 1 and 2 were found to be the first fluorescent organolead compounds.

AB - Reactions of 1,4-dilithio-1,2,3,4-tetraphenyl-1,3-butadiene with dichlorodiphenylplumbane gave hexaphenylplumbole 1 and spirobiplumbole 2. These structures were determined by X-ray diffraction analysis. Electronic structures of 1 and 2 were discussed by the aid of NMR analysis and theoretical calculations. The compounds 1 and 2 were found to be the first fluorescent organolead compounds.

KW - Fluorescence

KW - Hexaphenylplumbole

KW - Spirobiplumbole

KW - Theoretical calculation

KW - X-ray diffraction analysis

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SN - 1042-6507

VL - 185

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JF - Phosphorus, Sulfur and Silicon and the Related Elements

IS - 5-6

ER -

Synthesis, structures, and properties of plumboles

Abstract

Keywords

ASJC Scopus subject areas

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