Synthesis, structure and reactions of a trianion equivalent, trilithiostannane

Tomoyuki Tajima, Masatoshi Ikeda, Masaichi Saito, Kazuya Ishimura, Shigeru Nagase

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Transmetallation reaction of trisilylstannane ArSn(SiHMe2) 3 (Ar = 2,6-bis(2,4,6-triisopropylphenyl)phenyl), bearing a bulky substituent on the tin atom, with methyllithium in THF at room temperature gave the first trianion equivalent, trilithiostannane ArSnLi3, the generation of which was confirmed by trapping experiments with some electrophiles as well as by 119Sn and 7Li NMR spectroscopy.

Original languageEnglish
Pages (from-to)6495-6497
Number of pages3
JournalChemical Communications
Issue number48
DOIs
Publication statusPublished - Dec 11 2008
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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