Synthesis, structure and reactions of a trianion equivalent, trilithiostannane

Tomoyuki Tajima, Masatoshi Ikeda, Masaichi Saito, Kazuya Ishimura, Shigeru Nagase

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Transmetallation reaction of trisilylstannane ArSn(SiHMe2) 3 (Ar = 2,6-bis(2,4,6-triisopropylphenyl)phenyl), bearing a bulky substituent on the tin atom, with methyllithium in THF at room temperature gave the first trianion equivalent, trilithiostannane ArSnLi3, the generation of which was confirmed by trapping experiments with some electrophiles as well as by 119Sn and 7Li NMR spectroscopy.

Original languageEnglish
Pages (from-to)6495-6497
Number of pages3
JournalChemical Communications
Issue number48
DOIs
Publication statusPublished - 2008
Externally publishedYes

Fingerprint

Bearings (structural)
Tin
Nuclear magnetic resonance spectroscopy
Atoms
Experiments
Temperature
methyllithium

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Synthesis, structure and reactions of a trianion equivalent, trilithiostannane. / Tajima, Tomoyuki; Ikeda, Masatoshi; Saito, Masaichi; Ishimura, Kazuya; Nagase, Shigeru.

In: Chemical Communications, No. 48, 2008, p. 6495-6497.

Research output: Contribution to journalArticle

Tajima, Tomoyuki ; Ikeda, Masatoshi ; Saito, Masaichi ; Ishimura, Kazuya ; Nagase, Shigeru. / Synthesis, structure and reactions of a trianion equivalent, trilithiostannane. In: Chemical Communications. 2008 ; No. 48. pp. 6495-6497.
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