Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination

Manabu Kuroboshi, Katsuya Mizuno, Kiyoshi Kanie, Tamejiro Hiyama

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Oxidative desulfurization-fluorination of methyl N-pyridyl(or N-pyrimidyl)-N-alkyldithiocarbamates gave the corresponding trifluoromethylamino-substituted pyridines (or pyrimidines), which underwent cross-coupling reaction to give a new type of liquid crystalline compounds having trifluoromethylamino group.

Original languageEnglish
Pages (from-to)563-566
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number4
DOIs
Publication statusPublished - Jan 23 1995
Externally publishedYes

Fingerprint

Pyrimidines
Fluorination
Halogenation
Cross Reactions
Desulfurization
Crystalline materials
Liquids

Keywords

  • Dithiocarbamate
  • Oxidative desulfurization-fluorination
  • Trifluoromethylamine

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination. / Kuroboshi, Manabu; Mizuno, Katsuya; Kanie, Kiyoshi; Hiyama, Tamejiro.

In: Tetrahedron Letters, Vol. 36, No. 4, 23.01.1995, p. 563-566.

Research output: Contribution to journalArticle

Kuroboshi, Manabu ; Mizuno, Katsuya ; Kanie, Kiyoshi ; Hiyama, Tamejiro. / Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination. In: Tetrahedron Letters. 1995 ; Vol. 36, No. 4. pp. 563-566.
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