Synthesis of trifluoromethylamino-substituted pyridines and pyrimidines by oxidative desulfurization-fluorination

Manabu Kuroboshi, Katsuya Mizuno, Kiyoshi Kanie, Tamejiro Hiyama

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23 Citations (Scopus)

Abstract

Oxidative desulfurization-fluorination of methyl N-pyridyl(or N-pyrimidyl)-N-alkyldithiocarbamates gave the corresponding trifluoromethylamino-substituted pyridines (or pyrimidines), which underwent cross-coupling reaction to give a new type of liquid crystalline compounds having trifluoromethylamino group.

Original languageEnglish
Pages (from-to)563-566
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number4
DOIs
Publication statusPublished - Jan 23 1995
Externally publishedYes

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Keywords

  • Dithiocarbamate
  • Oxidative desulfurization-fluorination
  • Trifluoromethylamine

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

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