Synthesis of the E ring segment of ciguatoxin CTX3C via the negishi coupling of cyclic ketene acetal triflates

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2 Citations (Scopus)

Abstract

Stereocontrolled synthesis of the E ring segment of ciguatoxin CTX3C was performed via the Negishi coupling of cyclic ketene acetal triflates. Transformation of 8-membered lactones to the corresponding ketene acetal triflates was found to be affected by the protective groups of the substrates.

Original languageEnglish
Pages (from-to)997-1001
Number of pages5
JournalHeterocycles
Volume86
Issue number2
DOIs
Publication statusPublished - Dec 1 2012

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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