Synthesis of the E ring of gambierol

Isao Kadota, Chie Kadowaki, Noriko Yoshida, Yoshinori Yamamoto

Research output: Contribution to journalArticle

40 Citations (Scopus)

Abstract

The synthesis of the E ring of gambierol was achieved from D-ribose via the intramolecular reaction of allylstannane with an aldehyde as a key step. The undesired stereoisomer formed in this reaction was converted to the desired product by using DBU isomerization.

Original languageEnglish
Pages (from-to)6369-6372
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number35
DOIs
Publication statusPublished - Aug 27 1998
Externally publishedYes

Fingerprint

Stereoisomerism
Ribose
Isomerization
Aldehydes
gambierol

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Kadota, I., Kadowaki, C., Yoshida, N., & Yamamoto, Y. (1998). Synthesis of the E ring of gambierol. Tetrahedron Letters, 39(35), 6369-6372. https://doi.org/10.1016/S0040-4039(98)01311-2

Synthesis of the E ring of gambierol. / Kadota, Isao; Kadowaki, Chie; Yoshida, Noriko; Yamamoto, Yoshinori.

In: Tetrahedron Letters, Vol. 39, No. 35, 27.08.1998, p. 6369-6372.

Research output: Contribution to journalArticle

Kadota, I, Kadowaki, C, Yoshida, N & Yamamoto, Y 1998, 'Synthesis of the E ring of gambierol', Tetrahedron Letters, vol. 39, no. 35, pp. 6369-6372. https://doi.org/10.1016/S0040-4039(98)01311-2
Kadota, Isao ; Kadowaki, Chie ; Yoshida, Noriko ; Yamamoto, Yoshinori. / Synthesis of the E ring of gambierol. In: Tetrahedron Letters. 1998 ; Vol. 39, No. 35. pp. 6369-6372.
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