Synthesis of terminal-biradical compounds consisting of two N-oxyl groups connected with conjugated π-systems

Sigeru Torii, Tomoyuki Hase, Manabu Kuroboshi, Christian Amatore, Anny Jutand, Hiroyuki Kawafuchi

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Terminal-biradical compounds 1 having two N-oxyl groups connected with conjugated π-systems were synthesized by (1) addition of magnesium acetylide to 4-oxo-TEMPO, followed by dehydration, or (2) cross-coupling between acetylene and vinyl triflate derived from 4-oxo-TEMPO.

Original languageEnglish
Pages (from-to)7391-7394
Number of pages4
JournalTetrahedron Letters
Volume38
Issue number42
DOIs
Publication statusPublished - Oct 20 1997

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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