Synthesis of Sm3+-doped strontium barium niobate crystals in glass by samarium atom heat processing

Nakorn Chayapiwut, Tsuyoshi Honma, Yasuhiko Benino, Takumi Fujiwara, Takayuki Komatsu

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

New glasses giving the crystallization of Sm3+-doped Sr xBa1-xNb2O6 (SBN) ferroelectrics have been developed in the Sm2O3-SrO-BaO- Nb2O5-B2O3 system, and the formation of SBN crystal dots and lines by continuous wave Nd:YAG laser (wavelength:1064 nm, power: 1 W) irradiations, i.e., samarium atom heat processing, has been examined. The formation of Sm3+-doped SBN non-linear optical crystals is confirmed from X-ray diffraction analyses, micro-Raman scattering spectra, second harmonic generations, and photoluminescence spectra. Sm 3+-doped SBN crystal dots with the diameters of 20-70 μm and lines with the widths of 20-40 μm are written at the surface of some glasses such as 10Sm2O3·10SrO·10BaO·20Nb 2O5·50B2O3 (mol%) by Nd:YAG laser irradiations with the irradiation times of 20-70 s for the dots and with the scanning speeds of 1-5 μm/s for the lines. The present study suggests that the samarium atom heat processing has a potential for the patterning of optical waveguides consisting of ferroelectric SBN crystals in glass substrates.

Original languageEnglish
Pages (from-to)3507-3513
Number of pages7
JournalJournal of Solid State Chemistry
Volume178
Issue number11
DOIs
Publication statusPublished - Nov 2005
Externally publishedYes

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Keywords

  • Glasses
  • Laser-induced crystallization
  • Photoluminescence
  • Raman scattering spectra
  • SBN crystals

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

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