Synthesis of silyl formates, formamides, and aldehydesviasolvent-free organocatalytic hydrosilylation of CO2

Takumi Murata, Mahoko Hiyoshi, Manussada Ratanasak, Jun Ya Hasegawa, Tadashi Ema

Research output: Contribution to journalArticle

Abstract

Carbon dioxide (CO2) was used as a C1 source to prepare silyl formates, formamides, and aldehydes. Tetrabutylammonium acetate (TBAA) catalyzed the solvent-freeN-formylation of amines with CO2and hydrosilane to give formamides including Weinreb formamide, Me(MeO)NCHO, which was successively converted into aldehydes by one-pot reactions with Grignard reagents.

Original languageEnglish
Pages (from-to)5783-5786
Number of pages4
JournalChemical Communications
Volume56
Issue number43
DOIs
Publication statusPublished - May 28 2020

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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