TY - JOUR
T1 - Synthesis of silyl formates, formamides, and aldehydesviasolvent-free organocatalytic hydrosilylation of CO2
AU - Murata, Takumi
AU - Hiyoshi, Mahoko
AU - Ratanasak, Manussada
AU - Hasegawa, Jun Ya
AU - Ema, Tadashi
N1 - Funding Information:
This work was supported by the Yakumo Foundation for Environmental Science and by the Cooperative Research Program of Institute for Catalysis, Hokkaido University (Grant 19A1003). JH acknowledges MEXT for ‘‘Integrated Research Consortium on Chemical Sciences’’ and Hokkaido University for the ‘‘Photo-excitenix’’ project. Part of the computations were carried out at RCCS (Okazaki, Japan).
Publisher Copyright:
© The Royal Society of Chemistry 2020.
PY - 2020/5/28
Y1 - 2020/5/28
N2 - Carbon dioxide (CO2) was used as a C1 source to prepare silyl formates, formamides, and aldehydes. Tetrabutylammonium acetate (TBAA) catalyzed the solvent-freeN-formylation of amines with CO2and hydrosilane to give formamides including Weinreb formamide, Me(MeO)NCHO, which was successively converted into aldehydes by one-pot reactions with Grignard reagents.
AB - Carbon dioxide (CO2) was used as a C1 source to prepare silyl formates, formamides, and aldehydes. Tetrabutylammonium acetate (TBAA) catalyzed the solvent-freeN-formylation of amines with CO2and hydrosilane to give formamides including Weinreb formamide, Me(MeO)NCHO, which was successively converted into aldehydes by one-pot reactions with Grignard reagents.
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U2 - 10.1039/d0cc01371d
DO - 10.1039/d0cc01371d
M3 - Article
C2 - 32322865
AN - SCOPUS:85085590728
VL - 56
SP - 5783
EP - 5786
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 43
ER -