Abstract
The first synthesis of nitrogen-bridged terthiophenes (NBTTs) has been achieved by a tandem Buchwald-Hartwig coupling of 3,3′,3″,4′- tetrabromo-2,2′:5′,2″-terthiophene. Several NBTT derivatives bearing aryl or alkyl moieties on the N-atoms could be synthesized. Their fundamental electrochemical characteristics and HOMO-LUMO levels were found to be influenced by the substituents on the N-atoms.
| Original language | English |
|---|---|
| Pages (from-to) | 2702-2705 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 14 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Jun 1 2012 |
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ASJC Scopus subject areas
- Organic Chemistry
- Physical and Theoretical Chemistry
- Biochemistry
Cite this
Synthesis of nitrogen-bridged terthiophenes by tandem Buchwald-Hartwig coupling and their properties. / Mitsudo, Koichi; Shimohara, Shuichi; Mizoguchi, Jun; Mandai, Hiroki; Suga, Seiji.
In: Organic Letters, Vol. 14, No. 11, 01.06.2012, p. 2702-2705.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Synthesis of nitrogen-bridged terthiophenes by tandem Buchwald-Hartwig coupling and their properties
AU - Mitsudo, Koichi
AU - Shimohara, Shuichi
AU - Mizoguchi, Jun
AU - Mandai, Hiroki
AU - Suga, Seiji
PY - 2012/6/1
Y1 - 2012/6/1
N2 - The first synthesis of nitrogen-bridged terthiophenes (NBTTs) has been achieved by a tandem Buchwald-Hartwig coupling of 3,3′,3″,4′- tetrabromo-2,2′:5′,2″-terthiophene. Several NBTT derivatives bearing aryl or alkyl moieties on the N-atoms could be synthesized. Their fundamental electrochemical characteristics and HOMO-LUMO levels were found to be influenced by the substituents on the N-atoms.
AB - The first synthesis of nitrogen-bridged terthiophenes (NBTTs) has been achieved by a tandem Buchwald-Hartwig coupling of 3,3′,3″,4′- tetrabromo-2,2′:5′,2″-terthiophene. Several NBTT derivatives bearing aryl or alkyl moieties on the N-atoms could be synthesized. Their fundamental electrochemical characteristics and HOMO-LUMO levels were found to be influenced by the substituents on the N-atoms.
UR - http://www.scopus.com/inward/record.url?scp=84861828967&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84861828967&partnerID=8YFLogxK
U2 - 10.1021/ol300887t
DO - 10.1021/ol300887t
M3 - Article
C2 - 22594835
AN - SCOPUS:84861828967
VL - 14
SP - 2702
EP - 2705
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 11
ER -