TY - JOUR
T1 - Synthesis of microporous polymers with exposed C60 surfaces by polyesterification of fullerenol
AU - Nishihara, Hirotomo
AU - Harigaya, Akio
AU - Castro-Muñiz, Alberto
AU - Ohwada, Mao
AU - Kyotani, Takashi
AU - Nishina, Yuta
N1 - Publisher Copyright:
© 2022 The Royal Society of Chemistry.
PY - 2022
Y1 - 2022
N2 - Microporous polymers with exposed C60 surfaces have been synthesized by a new pathway of crosslinking fullerenol and terephthaloyl chloride or 1,3,5-benzenetricarbonyl trichloride via esterification. The resulting polymers are insoluble solids containing a large ratio of C60 with hydroxy groups and possess micropores with high specific surface area up to 657 m2 g−1. The microporous polymers thus obtained exhibit enhanced hydrogen spillover, which is a unique property of the C60 surface.
AB - Microporous polymers with exposed C60 surfaces have been synthesized by a new pathway of crosslinking fullerenol and terephthaloyl chloride or 1,3,5-benzenetricarbonyl trichloride via esterification. The resulting polymers are insoluble solids containing a large ratio of C60 with hydroxy groups and possess micropores with high specific surface area up to 657 m2 g−1. The microporous polymers thus obtained exhibit enhanced hydrogen spillover, which is a unique property of the C60 surface.
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U2 - 10.1039/d2cc00728b
DO - 10.1039/d2cc00728b
M3 - Article
C2 - 35665789
AN - SCOPUS:85131862928
SN - 1359-7345
JO - Chemical Communications
JF - Chemical Communications
ER -