Synthesis of (±)-Methyl Tuberonate, a Potato Tuber-forming Substance, and Its Epimer

Hiromasa Kiyota; Daisuke Nakashima; Takayuki Oritani

doi:10.1271/bbb.63.2110

Synthesis of (±)-Methyl Tuberonate, a Potato Tuber-forming Substance, and Its Epimer

Hiromasa Kiyota, Daisuke Nakashima, Takayuki Oritani

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Methyl esters of (±)-tuberonic acid and (±)-12-hydroxyjasmonic acid (trans-tuberonic acid), the aglycons of strong potato tuber-forming substances, were synthesized from norbornene via side-chain elongation and Baeyer-Villiger oxidation as key steps.

Original language	English
Pages (from-to)	2110-2117
Number of pages	8
Journal	Bioscience, Biotechnology and Biochemistry
Volume	63
Issue number	12
DOIs	https://doi.org/10.1271/bbb.63.2110
Publication status	Published - Jan 1 1999
Externally published	Yes

Keywords

Jasmonic acid
Methyl 12-hydroxyjasmonate
Methyl tuberonate
Potato tuberization
Total synthesis

ASJC Scopus subject areas

Biotechnology
Analytical Chemistry
Biochemistry
Applied Microbiology and Biotechnology
Molecular Biology
Organic Chemistry

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abstract = "Methyl esters of (±)-tuberonic acid and (±)-12-hydroxyjasmonic acid (trans-tuberonic acid), the aglycons of strong potato tuber-forming substances, were synthesized from norbornene via side-chain elongation and Baeyer-Villiger oxidation as key steps.",

keywords = "Jasmonic acid, Methyl 12-hydroxyjasmonate, Methyl tuberonate, Potato tuberization, Total synthesis",

author = "Hiromasa Kiyota and Daisuke Nakashima and Takayuki Oritani",

year = "1999",

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doi = "10.1271/bbb.63.2110",

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T1 - Synthesis of (±)-Methyl Tuberonate, a Potato Tuber-forming Substance, and Its Epimer

AU - Kiyota, Hiromasa

AU - Nakashima, Daisuke

AU - Oritani, Takayuki

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Methyl esters of (±)-tuberonic acid and (±)-12-hydroxyjasmonic acid (trans-tuberonic acid), the aglycons of strong potato tuber-forming substances, were synthesized from norbornene via side-chain elongation and Baeyer-Villiger oxidation as key steps.

AB - Methyl esters of (±)-tuberonic acid and (±)-12-hydroxyjasmonic acid (trans-tuberonic acid), the aglycons of strong potato tuber-forming substances, were synthesized from norbornene via side-chain elongation and Baeyer-Villiger oxidation as key steps.

KW - Jasmonic acid

KW - Methyl 12-hydroxyjasmonate

KW - Methyl tuberonate

KW - Potato tuberization

KW - Total synthesis

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U2 - 10.1271/bbb.63.2110

DO - 10.1271/bbb.63.2110

M3 - Article

AN - SCOPUS:0001724146

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VL - 63

SP - 2110

EP - 2117

JO - Bioscience, Biotechnology and Biochemistry

JF - Bioscience, Biotechnology and Biochemistry

IS - 12

ER -

Synthesis of (±)-Methyl Tuberonate, a Potato Tuber-forming Substance, and Its Epimer

Abstract

Keywords

ASJC Scopus subject areas

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