Abstract
Rhenium-catalyzed synthesis of naphthalene-substituted aryl bromides or iodides via C-H bond activation, and its use for palladium-catalyzed cross-coupling reactions with tetraethynylporphyrin are described. A series of novel meso-substituted tetraalkynylporphyrins with naphthalene moieties were obtained.
| Original language | English |
|---|---|
| Article number | U05111ST |
| Pages (from-to) | 2177-2180 |
| Number of pages | 4 |
| Journal | Synlett |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - Aug 31 2011 |
Keywords
- C-H bond activation
- Sonogashira coupling
- meso -substituted tetraalkynyl-porphyrin
- naphthalene derivative
- rhenium catalyst
ASJC Scopus subject areas
- Organic Chemistry
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Samarat, A., Kuninobu, Y., & Takai, K. (2011). Synthesis of meso-substituted tetraarylalkynylporphyrins via rhenium-catalyzed formation of naphthalene units. Synlett, (15), 2177-2180. [U05111ST]. https://doi.org/10.1055/s-0030-1261199