Synthesis of highly oxygenated biphenyl derivative in an optically active form through palladium-mediated intramolecular biaryl coupling reaction

Hitoshi Abe, Masatsugu Arai, Keisuke Nishioka, Tatsuya Kida, Kazuma Shioe, Yasuo Takeuchi, Takashi Harayama

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Optically active 6,6'-dihydroxymethyl-2,2'-3,3'-4,4'-hexamethoxybiphenyl (1) was prepared via the Pd-mediated biaryl coupling reaction of a phenyl benzoate derivative and the following enantioselective lactone opening reaction.

Original languageEnglish
Pages (from-to)291-303
Number of pages13
JournalHeterocycles
Volume76
Issue number1
DOIs
Publication statusPublished - 2008

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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