Synthesis of hexa(furan-2-yl)benzenes and their π-extended derivatives

Koichi Mitsudo, Jyunji Harada, Yo Tanaka, Hiroki Mandai, Chie Nishioka, Hideo Tanaka, Atsushi Wakamiya, Yasujiro Murata, Seiji Suga

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The first synthesis of hexa(furan-2-yl)benzene derivatives is described. The RhCl3/i-Pr2NEt-catalyzed cyclotrimerization of di(furan-2-yl)acetylenes was an effective method for constructing hexa(furan-2-yl)benzene derivatives in good yields. Their π-extended derivatives were also synthesized by Suzuki-Miyaura coupling between hexakis(5-Bpinfuran-2-yl)benzene (Bpin = (pinacolato)boryl) and several aryl iodides.

Original languageEnglish
Pages (from-to)2763-2768
Number of pages6
JournalJournal of Organic Chemistry
Volume78
Issue number6
DOIs
Publication statusPublished - Mar 15 2013

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Benzene
Benzene Derivatives
Derivatives
Alkynes
Iodides
furan

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Synthesis of hexa(furan-2-yl)benzenes and their π-extended derivatives. / Mitsudo, Koichi; Harada, Jyunji; Tanaka, Yo; Mandai, Hiroki; Nishioka, Chie; Tanaka, Hideo; Wakamiya, Atsushi; Murata, Yasujiro; Suga, Seiji.

In: Journal of Organic Chemistry, Vol. 78, No. 6, 15.03.2013, p. 2763-2768.

Research output: Contribution to journalArticle

Mitsudo, K, Harada, J, Tanaka, Y, Mandai, H, Nishioka, C, Tanaka, H, Wakamiya, A, Murata, Y & Suga, S 2013, 'Synthesis of hexa(furan-2-yl)benzenes and their π-extended derivatives', Journal of Organic Chemistry, vol. 78, no. 6, pp. 2763-2768. https://doi.org/10.1021/jo302652r
Mitsudo, Koichi ; Harada, Jyunji ; Tanaka, Yo ; Mandai, Hiroki ; Nishioka, Chie ; Tanaka, Hideo ; Wakamiya, Atsushi ; Murata, Yasujiro ; Suga, Seiji. / Synthesis of hexa(furan-2-yl)benzenes and their π-extended derivatives. In: Journal of Organic Chemistry. 2013 ; Vol. 78, No. 6. pp. 2763-2768.
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