Synthesis of cyclic 1-alkenylboronates via Zr-mediated double functionalization of alkynylboronates and sequential Ru-catalyzed ring-closing olefin metathesis

Yasushi Nishihara, Masato Suetsugu, Daisuke Saito, Megumi Kinoshita, Masayuki Iwasaki

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10 Citations (Scopus)

Abstract

Synthesis of novel cyclic 1-alkenylboronates is accomplished through the zirconium-mediated regio- and stereoselective double functionalization of 1-alkynylboronates and the subsequent ruthenium-catalyzed ring-closing metathesis (RCM). The obtained substituted cyclic 1-alkenylboronates are transformed into o-terphenyl and triphenylene derivatives.

Original languageEnglish
Pages (from-to)2418-2421
Number of pages4
JournalOrganic Letters
Volume15
Issue number10
DOIs
Publication statusPublished - May 17 2013

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ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

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