Synthesis of cross-conjugated trienes by rhodiumcatalyzed dimerization of monosubstituted allenes

Tomoya Miura; Tsuneaki Biyajima; Takeharu Toyoshima; Masahiro Murakami

doi:10.3762/bjoc.7.67

Synthesis of cross-conjugated trienes by rhodiumcatalyzed dimerization of monosubstituted allenes

Tomoya Miura, Tsuneaki Biyajima, Takeharu Toyoshima, Masahiro Murakami

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

Original language	English
Article number	A67
Pages (from-to)	578-581
Number of pages	4
Journal	Beilstein Journal of Organic Chemistry
Volume	7
DOIs	https://doi.org/10.3762/bjoc.7.67
Publication status	Published - May 9 2011
Externally published	Yes

Keywords

Allene
Cross-conjugated triene
Dimerization
Rhodium
Stereoselective

ASJC Scopus subject areas

Organic Chemistry

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10.3762/bjoc.7.67

Cite this

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title = "Synthesis of cross-conjugated trienes by rhodiumcatalyzed dimerization of monosubstituted allenes",

abstract = "A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.",

keywords = "Allene, Cross-conjugated triene, Dimerization, Rhodium, Stereoselective",

author = "Tomoya Miura and Tsuneaki Biyajima and Takeharu Toyoshima and Masahiro Murakami",

year = "2011",

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AU - Miura, Tomoya

AU - Biyajima, Tsuneaki

AU - Toyoshima, Takeharu

AU - Murakami, Masahiro

PY - 2011/5/9

Y1 - 2011/5/9

N2 - A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

AB - A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

KW - Allene

KW - Cross-conjugated triene

KW - Dimerization

KW - Rhodium

KW - Stereoselective

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M3 - Article

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JO - Beilstein Journal of Organic Chemistry

JF - Beilstein Journal of Organic Chemistry

SN - 1860-5397

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ER -

Synthesis of cross-conjugated trienes by rhodiumcatalyzed dimerization of monosubstituted allenes

Abstract

Keywords

ASJC Scopus subject areas

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