Synthesis of cross-conjugated trienes by rhodiumcatalyzed dimerization of monosubstituted allenes

Tomoya Miura, Tsuneaki Biyajima, Takeharu Toyoshima, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

A rhodium(I)/dppe catalyst promoted dimerization of monosubstituted allenes in a stereoselective manner to give cross-conjugated trienes, which are different from those obtained by a palladium catalyst.

Original languageEnglish
Article numberA67
Pages (from-to)578-581
Number of pages4
JournalBeilstein Journal of Organic Chemistry
Volume7
DOIs
Publication statusPublished - May 9 2011
Externally publishedYes

Keywords

  • Allene
  • Cross-conjugated triene
  • Dimerization
  • Rhodium
  • Stereoselective

ASJC Scopus subject areas

  • Organic Chemistry

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