Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescence

Chihiro Maeda; Keiji Nagahata; Kazuto Takaishi; Tadashi Ema

doi:10.1039/c9cc00894b

Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescence

Chihiro Maeda, Keiji Nagahata, Kazuto Takaishi, Tadashi Ema

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et₂AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularly polarized luminescence (CPL) both in solution and in the solid state.

Original language	English
Pages (from-to)	3136-3139
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	21
DOIs	https://doi.org/10.1039/c9cc00894b
Publication status	Published - 2019

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescence",

abstract = "Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et2AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularly polarized luminescence (CPL) both in solution and in the solid state.",

author = "Chihiro Maeda and Keiji Nagahata and Kazuto Takaishi and Tadashi Ema",

note = "Funding Information: This work was supported by the JSPS KAKENHI Grant Number 15K05427 and 18K05083, and the Wesco Scientific Promotion Foundation. We thank Prof. A. Osuka and Dr T. Tanaka (Kyoto University) for X-ray diffraction analysis and fluorescence measurements, and Prof. H. Yorimitsu (Kyoto University) for mass measurements. Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc00894b",

language = "English",

volume = "55",

pages = "3136--3139",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

number = "21",

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T1 - Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescence

AU - Maeda, Chihiro

AU - Nagahata, Keiji

AU - Takaishi, Kazuto

AU - Ema, Tadashi

N1 - Funding Information: This work was supported by the JSPS KAKENHI Grant Number 15K05427 and 18K05083, and the Wesco Scientific Promotion Foundation. We thank Prof. A. Osuka and Dr T. Tanaka (Kyoto University) for X-ray diffraction analysis and fluorescence measurements, and Prof. H. Yorimitsu (Kyoto University) for mass measurements. Publisher Copyright: © 2019 The Royal Society of Chemistry.

PY - 2019

Y1 - 2019

N2 - Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et2AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularly polarized luminescence (CPL) both in solution and in the solid state.

AB - Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et2AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularly polarized luminescence (CPL) both in solution and in the solid state.

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Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescence

Abstract

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