Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination

Manabu Kuroboshi, Masahiko Morita, Yasunari Masumoto, Masaki Mikasa, Ryohei Toza, Hideo Tanaka

Research output: Contribution to journalArticle


– We investigated the reaction between hexachlorocyclotriphosphazene ((NPCl2)3) and gaseous ammonia in several solvents to find that (NPCl2)2(NP(NH2)2) was obtained in solvents having low dielectric constant such as toluene and ether, whereas novel compound, (NPCl2)(NP(NH2)2)2, was selectively obtained in solvents having high dielectric constant such as acetonitrile.

Original languageEnglish
Pages (from-to)931-939
Number of pages9
Issue number7
Publication statusPublished - Jan 1 2019


ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

Cite this