Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination

Manabu Kuroboshi; Masahiko Morita; Yasunari Masumoto; Masaki Mikasa; Ryohei Toza; Hideo Tanaka

doi:10.3987/COM-19-14099

Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination

Manabu Kuroboshi, Masahiko Morita, Yasunari Masumoto, Masaki Mikasa, Ryohei Toza, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

– We investigated the reaction between hexachlorocyclotriphosphazene ((NPCl2)3) and gaseous ammonia in several solvents to find that (NPCl2)2(NP(NH2)2) was obtained in solvents having low dielectric constant such as toluene and ether, whereas novel compound, (NPCl2)(NP(NH2)2)2, was selectively obtained in solvents having high dielectric constant such as acetonitrile.

Original language	English
Pages (from-to)	931-939
Number of pages	9
Journal	Heterocycles
Volume	98
Issue number	7
DOIs	https://doi.org/10.3987/COM-19-14099
Publication status	Published - 2019

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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abstract = "– We investigated the reaction between hexachlorocyclotriphosphazene ((NPCl2)3) and gaseous ammonia in several solvents to find that (NPCl2)2(NP(NH2)2) was obtained in solvents having low dielectric constant such as toluene and ether, whereas novel compound, (NPCl2)(NP(NH2)2)2, was selectively obtained in solvents having high dielectric constant such as acetonitrile.",

author = "Manabu Kuroboshi and Masahiko Morita and Yasunari Masumoto and Masaki Mikasa and Ryohei Toza and Hideo Tanaka",

note = "Publisher Copyright: {\textcopyright} 2019 The Japan Institute of Heterocyclic Chemistry",

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T1 - Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination

AU - Kuroboshi, Manabu

AU - Morita, Masahiko

AU - Masumoto, Yasunari

AU - Mikasa, Masaki

AU - Toza, Ryohei

AU - Tanaka, Hideo

PY - 2019

Y1 - 2019

N2 - – We investigated the reaction between hexachlorocyclotriphosphazene ((NPCl2)3) and gaseous ammonia in several solvents to find that (NPCl2)2(NP(NH2)2) was obtained in solvents having low dielectric constant such as toluene and ether, whereas novel compound, (NPCl2)(NP(NH2)2)2, was selectively obtained in solvents having high dielectric constant such as acetonitrile.

AB - – We investigated the reaction between hexachlorocyclotriphosphazene ((NPCl2)3) and gaseous ammonia in several solvents to find that (NPCl2)2(NP(NH2)2) was obtained in solvents having low dielectric constant such as toluene and ether, whereas novel compound, (NPCl2)(NP(NH2)2)2, was selectively obtained in solvents having high dielectric constant such as acetonitrile.

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JO - Heterocycles

JF - Heterocycles

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IS - 7

ER -

Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination

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