Abstract
– We investigated the reaction between hexachlorocyclotriphosphazene ((NPCl2)3) and gaseous ammonia in several solvents to find that (NPCl2)2(NP(NH2)2) was obtained in solvents having low dielectric constant such as toluene and ether, whereas novel compound, (NPCl2)(NP(NH2)2)2, was selectively obtained in solvents having high dielectric constant such as acetonitrile.
| Original language | English |
|---|---|
| Pages (from-to) | 931-939 |
| Number of pages | 9 |
| Journal | Heterocycles |
| Volume | 98 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Jan 1 2019 |
ASJC Scopus subject areas
- Analytical Chemistry
- Pharmacology
- Organic Chemistry
Fingerprint Dive into the research topics of 'Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination'. Together they form a unique fingerprint.
Cite this
Kuroboshi, M., Morita, M., Masumoto, Y., Mikasa, M., Toza, R., & Tanaka, H. (2019). Synthesis of aminated cyclotriphosphazenes. Solvent effects on the product-selectivity of the amination. Heterocycles, 98(7), 931-939. https://doi.org/10.3987/COM-19-14099