Synthesis of a tetracyclic aminobenzimidazole derivative via tandem cyclization of triphenylguanidine

Yuki Akamatsu; Shinichiro Kamino; Daisuke Sawada

doi:10.3987/COM-18-S(F)61

Synthesis of a tetracyclic aminobenzimidazole derivative via tandem cyclization of triphenylguanidine

Yuki Akamatsu, Shinichiro Kamino, Daisuke Sawada

Research output: Contribution to journal › Article › peer-review

Abstract

We developed a new reaction for the one-pot synthesis of a fused cyclic compound from triphenylguanidine, which was thought to be tandem cyclization, with a moderate yield. In this reaction, conditions such as the metal reagent, oxidant, solvent, and ligand affected whether single or tandem cyclization was preferred.

Original language	English
Pages (from-to)	815-819
Number of pages	5
Journal	Heterocycles
Volume	99
Issue number	2
DOIs	https://doi.org/10.3987/COM-18-S(F)61
Publication status	Published - 2019

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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abstract = "We developed a new reaction for the one-pot synthesis of a fused cyclic compound from triphenylguanidine, which was thought to be tandem cyclization, with a moderate yield. In this reaction, conditions such as the metal reagent, oxidant, solvent, and ligand affected whether single or tandem cyclization was preferred.",

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