Synthesis of a novel zeolite through a pressure-induced reconstructive phase transition process

Jose L. Jordá, Fernando Rey, German Sastre, Susana Valencia, Miguel Palomino, Avelino Corma, Alfredo Segura, Daniel Errandonea, Raúl Lacomba, Francisco J. Manjón, Óscar Gomis, Annette K. Kleppe, Andrew P. Jephcoat, Mónica Amboage, J. Alberto Rodríguez-Velamazán

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

The first pressure-induced solid-phase synthesis of a zeolite has been found through compression of a common zeolite, ITQ-29 (see scheme, Si yellow, O red). The new microporous structure, ITQ-50, has a unique structure and improved performance for propene/propane separation with respect the parent material ITQ-29.

Original languageEnglish
Pages (from-to)10458-10462
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number40
DOIs
Publication statusPublished - Sep 27 2013
Externally publishedYes

Fingerprint

Zeolites
Propane
Propylene
Phase transitions
propylene

Keywords

  • adsorption
  • high-pressure chemistry
  • phase transitions
  • X-ray diffraction
  • zeolites

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Jordá, J. L., Rey, F., Sastre, G., Valencia, S., Palomino, M., Corma, A., ... Rodríguez-Velamazán, J. A. (2013). Synthesis of a novel zeolite through a pressure-induced reconstructive phase transition process. Angewandte Chemie - International Edition, 52(40), 10458-10462. https://doi.org/10.1002/anie.201305230

Synthesis of a novel zeolite through a pressure-induced reconstructive phase transition process. / Jordá, Jose L.; Rey, Fernando; Sastre, German; Valencia, Susana; Palomino, Miguel; Corma, Avelino; Segura, Alfredo; Errandonea, Daniel; Lacomba, Raúl; Manjón, Francisco J.; Gomis, Óscar; Kleppe, Annette K.; Jephcoat, Andrew P.; Amboage, Mónica; Rodríguez-Velamazán, J. Alberto.

In: Angewandte Chemie - International Edition, Vol. 52, No. 40, 27.09.2013, p. 10458-10462.

Research output: Contribution to journalArticle

Jordá, JL, Rey, F, Sastre, G, Valencia, S, Palomino, M, Corma, A, Segura, A, Errandonea, D, Lacomba, R, Manjón, FJ, Gomis, Ó, Kleppe, AK, Jephcoat, AP, Amboage, M & Rodríguez-Velamazán, JA 2013, 'Synthesis of a novel zeolite through a pressure-induced reconstructive phase transition process', Angewandte Chemie - International Edition, vol. 52, no. 40, pp. 10458-10462. https://doi.org/10.1002/anie.201305230
Jordá, Jose L. ; Rey, Fernando ; Sastre, German ; Valencia, Susana ; Palomino, Miguel ; Corma, Avelino ; Segura, Alfredo ; Errandonea, Daniel ; Lacomba, Raúl ; Manjón, Francisco J. ; Gomis, Óscar ; Kleppe, Annette K. ; Jephcoat, Andrew P. ; Amboage, Mónica ; Rodríguez-Velamazán, J. Alberto. / Synthesis of a novel zeolite through a pressure-induced reconstructive phase transition process. In: Angewandte Chemie - International Edition. 2013 ; Vol. 52, No. 40. pp. 10458-10462.
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