Abstract
The title sugar analogues (13) were synthesized by starting with known methyl (E)-5,6-dideoxy-2,3-O-isopropylidene-6-nitro-α-d-lyxo-hex-5-enofuranoside (5a) in six steps through the key intermediate, methyl 5-deoxy-5-dimethoxy-phosphinyl-2,3-O-isopropylidene-α-d-mannofuranoside 8a). The products (13) were converted into the corresponding penta-O-acetyl-5-methoxyphosphinyl derivatives (14), whose structures and conformations (mostly 4C1) were established by spectroscopy.
| Original language | English |
|---|---|
| Pages (from-to) | 2557-2564 |
| Number of pages | 8 |
| Journal | Heterocycles |
| Volume | 36 |
| Issue number | 11 |
| Publication status | Published - Nov 1 1993 |
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ASJC Scopus subject areas
- Analytical Chemistry
- Pharmacology
- Organic Chemistry
Cite this
Hanaya, T., Hirose, K., & Yamamoto, H. (1993). Synthesis of 5-deoxy-5-hydroxyphosphinyl-d-mannopyranoses. Heterocycles, 36(11), 2557-2564.