Abstract
The title sugar analogues (13) were synthesized by starting with known methyl (E)-5,6-dideoxy-2,3-O-isopropylidene-6-nitro-α-d-lyxo-hex-5-enofuranoside (5a) in six steps through the key intermediate, methyl 5-deoxy-5-dimethoxy-phosphinyl-2,3-O-isopropylidene-α-d-mannofuranoside 8a). The products (13) were converted into the corresponding penta-O-acetyl-5-methoxyphosphinyl derivatives (14), whose structures and conformations (mostly 4C1) were established by spectroscopy.
Original language | English |
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Pages (from-to) | 2557-2564 |
Number of pages | 8 |
Journal | Heterocycles |
Volume | 36 |
Issue number | 11 |
DOIs | |
Publication status | Published - Nov 1 1993 |
ASJC Scopus subject areas
- Analytical Chemistry
- Pharmacology
- Organic Chemistry