Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives

Koichi Mitsudo; Yuji Kurimoto; Hiroki Mandai; Seiji Suga

doi:10.1021/acs.orglett.7b00969

Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives

Koichi Mitsudo, Yuji Kurimoto, Hiroki Mandai, Seiji Suga

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The synthesis of 3-benzo[b]thienyl 3-thienyl ether and its dehydrogenative cyclization leading to benzodithienofuran (BDTF; [1]benzothieno[3,2-b]thieno[2,3-d]furan) are described for the first time. Further transformation of BDTF to more π-extended BDTF derivatives and their fundamental physical properties are also studied.

Original language	English
Pages (from-to)	2821-2824
Number of pages	4
Journal	Organic Letters
Volume	19
Issue number	11
DOIs	https://doi.org/10.1021/acs.orglett.7b00969
Publication status	Published - Jun 2 2017

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton : Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives. / Mitsudo, Koichi; Kurimoto, Yuji; Mandai, Hiroki et al.

In: Organic Letters, Vol. 19, No. 11, 02.06.2017, p. 2821-2824.

Research output: Contribution to journal › Article › peer-review

Mitsudo, K, Kurimoto, Y, Mandai, H & Suga, S 2017, 'Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives', Organic Letters, vol. 19, no. 11, pp. 2821-2824. https://doi.org/10.1021/acs.orglett.7b00969

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abstract = "The synthesis of 3-benzo[b]thienyl 3-thienyl ether and its dehydrogenative cyclization leading to benzodithienofuran (BDTF; [1]benzothieno[3,2-b]thieno[2,3-d]furan) are described for the first time. Further transformation of BDTF to more π-extended BDTF derivatives and their fundamental physical properties are also studied.",

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AU - Mandai, Hiroki

AU - Suga, Seiji

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Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives

Abstract

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