Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives

Koichi Mitsudo, Yuji Kurimoto, Hiroki Mandai, Seiji Suga

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The synthesis of 3-benzo[b]thienyl 3-thienyl ether and its dehydrogenative cyclization leading to benzodithienofuran (BDTF; [1]benzothieno[3,2-b]thieno[2,3-d]furan) are described for the first time. Further transformation of BDTF to more π-extended BDTF derivatives and their fundamental physical properties are also studied.

Original languageEnglish
Pages (from-to)2821-2824
Number of pages4
JournalOrganic Letters
Volume19
Issue number11
DOIs
Publication statusPublished - Jun 2 2017

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furans
Cyclization
musculoskeletal system
Skeleton
Ether
elimination
ethers
Physical properties
physical properties
Oxygen
Derivatives
oxygen
synthesis
furan
thieno(3,2-b)furan

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

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title = "Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton: Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives",
abstract = "The synthesis of 3-benzo[b]thienyl 3-thienyl ether and its dehydrogenative cyclization leading to benzodithienofuran (BDTF; [1]benzothieno[3,2-b]thieno[2,3-d]furan) are described for the first time. Further transformation of BDTF to more π-extended BDTF derivatives and their fundamental physical properties are also studied.",
author = "Koichi Mitsudo and Yuji Kurimoto and Hiroki Mandai and Seiji Suga",
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language = "English",
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journal = "Organic Letters",
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publisher = "American Chemical Society",
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TY - JOUR

T1 - Synthesis of 3-Benzo[b]thienyl 3-Thienyl Ether via an Addition-Elimination Reaction and Its Transformation to an Oxygen-Fused Dithiophene Skeleton

T2 - Synthesis and Properties of Benzodithienofuran and Its π-Extended Derivatives

AU - Mitsudo, Koichi

AU - Kurimoto, Yuji

AU - Mandai, Hiroki

AU - Suga, Seiji

PY - 2017/6/2

Y1 - 2017/6/2

N2 - The synthesis of 3-benzo[b]thienyl 3-thienyl ether and its dehydrogenative cyclization leading to benzodithienofuran (BDTF; [1]benzothieno[3,2-b]thieno[2,3-d]furan) are described for the first time. Further transformation of BDTF to more π-extended BDTF derivatives and their fundamental physical properties are also studied.

AB - The synthesis of 3-benzo[b]thienyl 3-thienyl ether and its dehydrogenative cyclization leading to benzodithienofuran (BDTF; [1]benzothieno[3,2-b]thieno[2,3-d]furan) are described for the first time. Further transformation of BDTF to more π-extended BDTF derivatives and their fundamental physical properties are also studied.

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U2 - 10.1021/acs.orglett.7b00969

DO - 10.1021/acs.orglett.7b00969

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JO - Organic Letters

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