Synthesis, characterization, and controlling morphology of an aryl ether dendrimer containing a dichalcogenide bond as the core

Yutaka Takaguchi, S. Suzuki, T. Mori, J. Motoyoshiya, H. Aoyama

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

A poly(benzyl ether) dendron with a thiol group or a selenocyanate group at the focal point was synthesized and well characterized, and then used for the controlling morphology. The molecules show a reversible redox behavior between dendrons and dendrimer dichalcogenides, being achieved under chemical reactions, although a dendrimer having selenium atoms has never been reported. Furthermore, dendrimer dichalcogenides underwent an dechalcogenation reaction upon a treatment with hexaethylphosphorous triamide or photoirradiation to give dendrimer chalcogenides.

Original languageEnglish
Pages (from-to)1857-1860
Number of pages4
JournalBulletin of the Chemical Society of Japan
Volume73
Issue number8
DOIs
Publication statusPublished - Aug 2000
Externally publishedYes

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Dendrimers
Ether
Chalcogenides
Selenium
Sulfhydryl Compounds
Chemical reactions
Atoms
Molecules

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis, characterization, and controlling morphology of an aryl ether dendrimer containing a dichalcogenide bond as the core. / Takaguchi, Yutaka; Suzuki, S.; Mori, T.; Motoyoshiya, J.; Aoyama, H.

In: Bulletin of the Chemical Society of Japan, Vol. 73, No. 8, 08.2000, p. 1857-1860.

Research output: Contribution to journalArticle

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