Synthesis and structures of polychalcogenadistannabicyclo[k.l.m]alkanes

Masaichi Saito, Hizuru Hashimoto, Tomoyuki Tajima, Masatoshi Ikeda

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Reaction of steric encumbered trichlorostannane with disodium sulfide or dilithium selenide gave 2,4-dimercapto-1,3,2,4-dithiadistannetane or tetraselenadistannabicyclo[2.1.1]hexane, respectively. Reactions of steric encumbered trihydrostannane with elemental chalcogens gave pentachalcogenadistannabicyclo[k.1.1]heptanes (k = 2 and 3). The two bridgehead tin atoms of the first polychalcogenadistannabicyclo[k.l.m]alkanes are concluded to have no significant bonding interaction, judging from the longer bond distances than those of the normal tin-tin single bonds.

Original languageEnglish
Pages (from-to)2729-2735
Number of pages7
JournalJournal of Organometallic Chemistry
Volume692
Issue number13
DOIs
Publication statusPublished - Jun 1 2007
Externally publishedYes

Keywords

  • Polychalcogenadistannabicyclo[k.l.m]alkanes
  • Selenium
  • Sulfur
  • Tin

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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