Synthesis and structures of monomeric group 14 triols and their reactivity

Lucian Cristian Pop; Nobuaki Kurokawa; Hiroaki Ebata; Katsuya Tomizawa; Tomoyuki Tajima; Masatoshi Ikeda; Michikazu Yoshioka; Monique Biesemans; Rudolph Willem; Mao Minoura; Masaichi Saito

doi:10.1139/cjc-2013-0496

Synthesis and structures of monomeric group 14 triols and their reactivity

Lucian Cristian Pop, Nobuaki Kurokawa, Hiroaki Ebata, Katsuya Tomizawa, Tomoyuki Tajima, Masatoshi Ikeda, Michikazu Yoshioka, Monique Biesemans, Rudolph Willem, Mao Minoura, Masaichi Saito

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and-germane.The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy.The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn-O-Si-O-Sn linkages in the molecule.All the group 14 triols can be converted to the corresponding trihalo compounds in good yields.

Original language	English
Pages (from-to)	542-548
Number of pages	7
Journal	Canadian Journal of Chemistry
Volume	92
Issue number	6
DOIs	https://doi.org/10.1139/cjc-2013-0496
Publication status	Published - Jun 2014
Externally published	Yes

Keywords

Cyclostannasiloxane
Germanetriol
Silicone grease
Stannanetriol

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Organic Chemistry

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10.1139/cjc-2013-0496

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title = "Synthesis and structures of monomeric group 14 triols and their reactivity",

abstract = "The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and-germane.The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy.The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn-O-Si-O-Sn linkages in the molecule.All the group 14 triols can be converted to the corresponding trihalo compounds in good yields.",

keywords = "Cyclostannasiloxane, Germanetriol, Silicone grease, Stannanetriol",

author = "Pop, {Lucian Cristian} and Nobuaki Kurokawa and Hiroaki Ebata and Katsuya Tomizawa and Tomoyuki Tajima and Masatoshi Ikeda and Michikazu Yoshioka and Monique Biesemans and Rudolph Willem and Mao Minoura and Masaichi Saito",

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doi = "10.1139/cjc-2013-0496",

language = "English",

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publisher = "National Research Council of Canada",

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TY - JOUR

T1 - Synthesis and structures of monomeric group 14 triols and their reactivity

AU - Pop, Lucian Cristian

AU - Kurokawa, Nobuaki

AU - Ebata, Hiroaki

AU - Tomizawa, Katsuya

AU - Tajima, Tomoyuki

AU - Ikeda, Masatoshi

AU - Yoshioka, Michikazu

AU - Biesemans, Monique

AU - Willem, Rudolph

AU - Minoura, Mao

AU - Saito, Masaichi

PY - 2014/6

Y1 - 2014/6

N2 - The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and-germane.The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy.The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn-O-Si-O-Sn linkages in the molecule.All the group 14 triols can be converted to the corresponding trihalo compounds in good yields.

AB - The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and-germane.The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy.The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn-O-Si-O-Sn linkages in the molecule.All the group 14 triols can be converted to the corresponding trihalo compounds in good yields.

KW - Cyclostannasiloxane

KW - Germanetriol

KW - Silicone grease

KW - Stannanetriol

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DO - 10.1139/cjc-2013-0496

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EP - 548

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 6

ER -

Synthesis and structures of monomeric group 14 triols and their reactivity

Abstract

Keywords

ASJC Scopus subject areas

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