Synthesis and structures of monomeric group 14 triols and their reactivity

Lucian Cristian Pop, Nobuaki Kurokawa, Hiroaki Ebata, Katsuya Tomizawa, Tomoyuki Tajima, Masatoshi Ikeda, Michikazu Yoshioka, Monique Biesemans, Rudolph Willem, Mao Minoura, Masaichi Saito

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and-germane.The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy.The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn-O-Si-O-Sn linkages in the molecule.All the group 14 triols can be converted to the corresponding trihalo compounds in good yields.

Original languageEnglish
Pages (from-to)542-548
Number of pages7
JournalCanadian Journal of Chemistry
Volume92
Issue number6
DOIs
Publication statusPublished - Jun 2014
Externally publishedYes

Keywords

  • Cyclostannasiloxane
  • Germanetriol
  • Silicone grease
  • Stannanetriol

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Organic Chemistry

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