Synthesis and structure of a kinetically stabilized stannanethione

Tomoyuki Tajima, Takahiro Sasamori, Nobuhiro Takeda, Norihiro Tokitoh

Research output: Contribution to journalArticlepeer-review

7 Citations (Scopus)

Abstract

The X-ray crystallographic analysis of a stable stannanethione, Bbt(Titp)Sn=S, reveals that the tin-sulfur bond distance [2.221(3) Å] is ca. 10% shorter than the normal tin-sulfur single bonds and the tin atom of the stannanethione has a trigonal planar geometry, as do as the carbonyl carbon atoms.

Original languageEnglish
Pages (from-to)1202-1204
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume80
Issue number6
DOIs
Publication statusPublished - 2007
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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