Synthesis and structural revision of symbiodinolide C23-C34 fragment

Takeshi Murata; Masayuki Sano; Hiroyoshi Takamura; Isao Kadota; Daisuke Uemura

doi:10.1021/jo900546k

Synthesis and structural revision of symbiodinolide C23-C34 fragment

Takeshi Murata, Masayuki Sano, Hiroyoshi Takamura, Isao Kadota, Daisuke Uemura

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

(Chemical Equation Presented) Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.

Original language	English
Pages (from-to)	4797-4803
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	74
Issue number	13
DOIs	https://doi.org/10.1021/jo900546k
Publication status	Published - Jul 3 2009

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo900546k

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AU - Murata, Takeshi

AU - Sano, Masayuki

AU - Takamura, Hiroyoshi

AU - Kadota, Isao

AU - Uemura, Daisuke

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Synthesis and structural revision of symbiodinolide C23-C34 fragment

Abstract

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