Synthesis and structural revision of symbiodinolide C23-C34 fragment

Takeshi Murata, Masayuki Sano, Hiroyoshi Takamura, Isao Kadota, Daisuke Uemura

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

(Chemical Equation Presented) Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.

Original languageEnglish
Pages (from-to)4797-4803
Number of pages7
JournalJournal of Organic Chemistry
Volume74
Issue number13
DOIs
Publication statusPublished - Jul 3 2009

ASJC Scopus subject areas

  • Organic Chemistry

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