Synthesis and structural revision of symbiodinolide C23-C34 fragment

Takeshi Murata; Masayuki Sano; Hiroyoshi Takamura; Isao Kadota; Daisuke Uemura

doi:10.1021/jo900546k

Synthesis and structural revision of symbiodinolide C23-C34 fragment

Takeshi Murata, Masayuki Sano, Hiroyoshi Takamura, Isao Kadota, Daisuke Uemura

Research output: Contribution to journal › Article

25 Citations (Scopus)

Abstract

(Chemical Equation Presented) Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.

Original language	English
Pages (from-to)	4797-4803
Number of pages	7
Journal	Journal of Organic Chemistry
Volume	74
Issue number	13
DOIs	https://doi.org/10.1021/jo900546k
Publication status	Published - Jul 3 2009

ASJC Scopus subject areas

Organic Chemistry

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Murata, T., Sano, M., Takamura, H., Kadota, I., & Uemura, D. (2009). Synthesis and structural revision of symbiodinolide C23-C34 fragment. Journal of Organic Chemistry, 74(13), 4797-4803. https://doi.org/10.1021/jo900546k

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AU - Uemura, Daisuke

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