Abstract
(Chemical Equation Presented) Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.
| Original language | English |
|---|---|
| Pages (from-to) | 4797-4803 |
| Number of pages | 7 |
| Journal | Journal of Organic Chemistry |
| Volume | 74 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - Jul 3 2009 |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Synthesis and structural revision of symbiodinolide C23-C34 fragment. / Murata, Takeshi; Sano, Masayuki; Takamura, Hiroyoshi; Kadota, Isao; Uemura, Daisuke.
In: Journal of Organic Chemistry, Vol. 74, No. 13, 03.07.2009, p. 4797-4803.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and structural revision of symbiodinolide C23-C34 fragment
AU - Murata, Takeshi
AU - Sano, Masayuki
AU - Takamura, Hiroyoshi
AU - Kadota, Isao
AU - Uemura, Daisuke
PY - 2009/7/3
Y1 - 2009/7/3
N2 - (Chemical Equation Presented) Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.
AB - (Chemical Equation Presented) Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.
UR - http://www.scopus.com/inward/record.url?scp=67649625261&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=67649625261&partnerID=8YFLogxK
U2 - 10.1021/jo900546k
DO - 10.1021/jo900546k
M3 - Article
VL - 74
SP - 4797
EP - 4803
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
SN - 0022-3263
IS - 13
ER -