Synthesis and structural revision of symbiodinolide C23-C34 fragment

Takeshi Murata, Masayuki Sano, Hiroyoshi Takamura, Isao Kadota, Daisuke Uemura

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

(Chemical Equation Presented) Stereoselective synthesis of the C23-C34 fragment of symbiodinolide, which possesses the originally proposed stereochemistry, and its diastereomers was achieved in 19 steps from L-aspartic acid, respectively. Comparison of spectroscopic data of the synthetic products with those of the degraded product of symbiodinolide led to a structural revision of the C23-C34 fragment.

Original languageEnglish
Pages (from-to)4797-4803
Number of pages7
JournalJournal of Organic Chemistry
Volume74
Issue number13
DOIs
Publication statusPublished - Jul 3 2009

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Stereochemistry
Aspartic Acid
symbiodinolide

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Synthesis and structural revision of symbiodinolide C23-C34 fragment. / Murata, Takeshi; Sano, Masayuki; Takamura, Hiroyoshi; Kadota, Isao; Uemura, Daisuke.

In: Journal of Organic Chemistry, Vol. 74, No. 13, 03.07.2009, p. 4797-4803.

Research output: Contribution to journalArticle

Murata, Takeshi ; Sano, Masayuki ; Takamura, Hiroyoshi ; Kadota, Isao ; Uemura, Daisuke. / Synthesis and structural revision of symbiodinolide C23-C34 fragment. In: Journal of Organic Chemistry. 2009 ; Vol. 74, No. 13. pp. 4797-4803.
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