Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride

Yutaka Takaguchi, Naomichi Furukawa

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.

Original languageEnglish
Pages (from-to)365-366
Number of pages2
JournalChemistry Letters
Issue number5
Publication statusPublished - 1996
Externally publishedYes

Fingerprint

Tellurium
Crystal structure
X rays
Geometry
lithium aluminum hydride

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{935440de42be4982a6a5722156371d0c,
title = "Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)]): Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride",
abstract = "Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.",
author = "Yutaka Takaguchi and Naomichi Furukawa",
year = "1996",
language = "English",
pages = "365--366",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "5",

}

TY - JOUR

T1 - Synthesis and structural determination of 1,1′-spirobi(3H-2,1-benzoxatellurole)-3-one ([10-Te-4(C2O2)])

T2 - Conversion of diacyloxyspirotellurane to alkoxyspirotellurane by reduction with lithium aluminium hydride

AU - Takaguchi, Yutaka

AU - Furukawa, Naomichi

PY - 1996

Y1 - 1996

N2 - Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.

AB - Selective reduction of the diacyloxyspirotellurane 1 with lithium aluminium hydride gave the acyloxyalkoxyspirotellurane 2 and dialkoxyspirotellurane 3, respectively. The X-ray crystal structure analysis of 2 (R = 0.020) reveals distorted trigonal-bipyramidal geometry about tellurium, similar to structures previously determined for other spirotelluranes.

UR - http://www.scopus.com/inward/record.url?scp=0030488577&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030488577&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0030488577

SP - 365

EP - 366

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 5

ER -