Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2

Yasushi Nishihara; Hiroyuki Onodera; Kohtaro Osakada

doi:10.1039/b308741g

Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PEt₃)₂, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C₆F₅)I(PEt₃)₂

Yasushi Nishihara, Hiroyuki Onodera, Kohtaro Osakada

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C₆F₅)I(PR₃)₂(PR₃=PEt₃, PMe₂Ph, PMePh₂) in the presence of Ag₂O afforded trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PR₃)₂ which are stabilized by fluorine atoms in the ortho positions.

Original language	English
Pages (from-to)	192-193
Number of pages	2
Journal	Chemical Communications
Volume	4
Issue number	2
DOIs	https://doi.org/10.1039/b308741g
Publication status	Published - Jan 1 2004
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PEt₃)₂, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C₆F₅)I(PEt₃)₂. / Nishihara, Yasushi; Onodera, Hiroyuki; Osakada, Kohtaro.

In: Chemical Communications, Vol. 4, No. 2, 01.01.2004, p. 192-193.

Research output: Contribution to journal › Article › peer-review

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abstract = "The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C6F5)I(PR3)2(PR3=PEt3, PMe2Ph, PMePh2) in the presence of Ag2O afforded trans-Pd(C6F5)(2,4,6-C6F3H2)(PR3)2 which are stabilized by fluorine atoms in the ortho positions.",

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