Abstract
The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C6F5)I(PR3)2(PR3=PEt3, PMe2Ph, PMePh2) in the presence of Ag2O afforded trans-Pd(C6F5)(2,4,6-C6F3H2)(PR3)2 which are stabilized by fluorine atoms in the ortho positions.
| Original language | English |
|---|---|
| Pages (from-to) | 192-193 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Volume | 4 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Jan 1 2004 |
| Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
Fingerprint Dive into the research topics of 'Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C<sub>6</sub>F<sub>5</sub>)(2,4,6-C<sub>6</sub>F<sub>3</sub>H<sub>2</sub>)(PEt<sub>3</sub>)<sub>2</sub>, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C<sub>6</sub>F<sub>5</sub>)I(PEt<sub>3</sub>)<sub>2</sub>'. Together they form a unique fingerprint.
Cite this
Nishihara, Y., Onodera, H., & Osakada, K. (2004). Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2. Chemical Communications, 4(2), 192-193. https://doi.org/10.1039/b308741g