Synthesis and structural analyses of 3-acetamido-1,4-di-O-acetyl-2,3,5-trideoxy-5-C-(isopropylphosphinyl)-D- erythro-pentopyranoses

Tatsuo Oshikawa, Kuniaki Seo, Mitsuji Yamashita, Tadashi Hanaya, Yoshihiro Hamauzu, Hiroshi Yamamoto

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

1H NMR spectroscopy of phosphorus containing hetero sugars (phospha sugars), revealed the α and β configurations and chair conformations for 3-acetamido-1,4-di-O-acetyl-2,3,5-trideoxy-5-C-(isopropylphosphinyl)-α- and β-D-erythro-pentopyranoses. The conformation of the title compounds was determined by 1H NMR as 1C4 in CDCl3 and the conformation was in accord with that in solid state determined by X-ray crystallographic analysis.

Original languageEnglish
Pages (from-to)283-291
Number of pages9
JournalCarbohydrate Research
Volume338
Issue number3
DOIs
Publication statusPublished - Jan 31 2003

Keywords

  • C conformation
  • NMR
  • Phospha sugar
  • X-ray

ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Synthesis and structural analyses of 3-acetamido-1,4-di-O-acetyl-2,3,5-trideoxy-5-C-(isopropylphosphinyl)-D- erythro-pentopyranoses'. Together they form a unique fingerprint.

  • Cite this