Abstract
The synthesis of a dimeric boryloxorhodium complex having the Rh-O-Bpin scaffold from the reaction of [(cod)Rh(OMe)]2or [(cod)Rh(OH)]2with an arylboronate has been achieved. The obtained dirhodium complex is converted into mononuclear complex [(cod)Rh(OBpin)(PPh3)], which reacts with arylboronic acid to afford the complex with an Rh-aryl bondviatransmetalation from boron to rhodium. The dimeric boryloxorhodium complex catalyzes the 1,4-addition of arylboronic acid to cyclohexene-2-one.
Original language | English |
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Pages (from-to) | 3610-3615 |
Number of pages | 6 |
Journal | Dalton Transactions |
Volume | 50 |
Issue number | 10 |
DOIs | |
Publication status | Published - Mar 14 2021 |
Externally published | Yes |
ASJC Scopus subject areas
- Inorganic Chemistry