TY - JOUR
T1 - Synthesis and properties of (Terthiophene)4 - Poly(amidoamine) - C60 pentad
AU - Tajima, Tomoyuki
AU - Nishihama, Takuya
AU - Miyake, Shogo
AU - Takahashi, Nobuhiro
AU - Takaguchi, Yutaka
N1 - Publisher Copyright:
© 2015 The Chemical Society of Japan.
PY - 2015
Y1 - 2015
N2 - (Terthiophene)4 - poly(amidoamine) - C60 pentad 8a and (terthiophene)2 - poly(amidoamine) - C60 triad 8b have been synthesized with the aim of developing novel precursors for photoinduced polymerization. The electrochemical oxidation of pentad 8a by repetitive cyclic voltammogram scans gave a polymeric 8a film on a FTO electrode, which showed electrochemical activity and photoelectric response. When a monomer film of 8 on FTO was irradiated with visible light, the photoinduced polymerization of the terthiophene moiety was observed. The photoanodic features of an electropolymerized film of 8a on a FTO (poly-8aelectro/FTO) and 8a/FTO were investigated regarding photocurrent response to light irradiation. The photocurrent of a photopolymerized 8a film on a FTO (poly-8aphoto/FTO) electrode formed by photoreaction of 8a/FTO, is approximately 6 times greater than that of the 8a/FTO electrode.
AB - (Terthiophene)4 - poly(amidoamine) - C60 pentad 8a and (terthiophene)2 - poly(amidoamine) - C60 triad 8b have been synthesized with the aim of developing novel precursors for photoinduced polymerization. The electrochemical oxidation of pentad 8a by repetitive cyclic voltammogram scans gave a polymeric 8a film on a FTO electrode, which showed electrochemical activity and photoelectric response. When a monomer film of 8 on FTO was irradiated with visible light, the photoinduced polymerization of the terthiophene moiety was observed. The photoanodic features of an electropolymerized film of 8a on a FTO (poly-8aelectro/FTO) and 8a/FTO were investigated regarding photocurrent response to light irradiation. The photocurrent of a photopolymerized 8a film on a FTO (poly-8aphoto/FTO) electrode formed by photoreaction of 8a/FTO, is approximately 6 times greater than that of the 8a/FTO electrode.
UR - http://www.scopus.com/inward/record.url?scp=84934903762&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84934903762&partnerID=8YFLogxK
U2 - 10.1246/bcsj.20140283
DO - 10.1246/bcsj.20140283
M3 - Article
AN - SCOPUS:84934903762
SN - 0009-2673
VL - 88
SP - 736
EP - 745
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 5
ER -