Synthesis and Properties of Ethene-Bridged Terthiophenes

Koichi Mitsudo, Hidehiko Sato, Arata Yamasaki, Natsuyo Kamimoto, Jun Goto, Hiroki Mandai, Seiji Suga

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

A method for the facile synthesis of ethene-bridged terthiophenes (EBTTs) in two steps has been developed. The first step is a double Sonogashira coupling between 3′,4′-dibromo-2,2′:5′,2″-terthiophene and terminal alkynes to give dialkynylated terthiophenes, and the second step is a cyclization reaction to afford EBTTs. The fundamental physical properties of EBTTs were also studied.

Original languageEnglish
Pages (from-to)4858-4861
Number of pages4
JournalOrganic Letters
Volume17
Issue number19
DOIs
Publication statusPublished - Oct 2 2015

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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