Synthesis and Properties of Dithieno-Fused 1,4-Azaborine Derivatives

Koichi Mitsudo, Keisuke Shigemori, Hiroki Mandai, Atsushi Wakamiya, Seiji Suga

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

The first synthesis of dithieno[3,2-b:2′,3′-e][1,4]azaborinine (DTAB) derivatives has been achieved by Buchwald-Hartwig coupling and subsequent Friedel-Crafts-type C-H borylation. A facile method for further π-extension of DTAB was also developed via stannylation and subsequent Kosugi-Migita-Stille cross-coupling reaction. The fundamental properties of DTAB derivatives were also investigated. ©

Original languageEnglish
Pages (from-to)7336-7340
Number of pages5
JournalOrganic Letters
Volume20
Issue number22
DOIs
Publication statusPublished - Nov 16 2018

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cross coupling
vehicles
Derivatives
synthesis
Cross Reactions
decyltrimethylammonium

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Synthesis and Properties of Dithieno-Fused 1,4-Azaborine Derivatives. / Mitsudo, Koichi; Shigemori, Keisuke; Mandai, Hiroki; Wakamiya, Atsushi; Suga, Seiji.

In: Organic Letters, Vol. 20, No. 22, 16.11.2018, p. 7336-7340.

Research output: Contribution to journal › Article

Mitsudo, K, Shigemori, K, Mandai, H, Wakamiya, A & Suga, S 2018, 'Synthesis and Properties of Dithieno-Fused 1,4-Azaborine Derivatives', Organic Letters, vol. 20, no. 22, pp. 7336-7340. https://doi.org/10.1021/acs.orglett.8b03316
Mitsudo K, Shigemori K, Mandai H, Wakamiya A, Suga S. Synthesis and Properties of Dithieno-Fused 1,4-Azaborine Derivatives. Organic Letters. 2018 Nov 16;20(22):7336-7340. https://doi.org/10.1021/acs.orglett.8b03316
Mitsudo, Koichi ; Shigemori, Keisuke ; Mandai, Hiroki ; Wakamiya, Atsushi ; Suga, Seiji. / Synthesis and Properties of Dithieno-Fused 1,4-Azaborine Derivatives. In: Organic Letters. 2018 ; Vol. 20, No. 22. pp. 7336-7340.
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