Synthesis and photoproperties of edge-functionalized zeolite-templated carbon with bromine or carbazole groups

Haruko Goto, Tomoyuki Tajima, Kazumasa Kobayashi, Yutaka Takaguchi, Khanin Nueangnoraj, Hirotomo Nishihara

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

We succeeded in synthesizing edge-brominated zeolite-templated carbon (ZTC-Br) as the key intermediate of edge-functionalization of ZTC via an electrophilic aromatic substitution reaction using dibromoisocyanuric acid. ZTC-Br was easily converted into carbazole-modified ZTC (ZTC-Cz) using Suzuki-Miyaura coupling. Interestingly, solvent-dependent changes of the fluorescence intensity of ZTC-Cz owing to its swelling-shrinking behavior were observed.

Original languageEnglish
Pages (from-to)601-603
Number of pages3
JournalChemistry Letters
Volume45
Issue number6
DOIs
Publication statusPublished - 2016

Keywords

  • Solvatochromism
  • Suzuki-Miyaura cross coupling
  • Zeolite-templated carbon (ZTC)

ASJC Scopus subject areas

  • Chemistry(all)

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