Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates

Yanying Zhang, Song Tu, Koichi Mitsudo, Hideo Tanaka, Shunzo Suematsu, Kenji Machida, Daisuke Horii, Shuichi Ishimoto, Kenji Tamamitsu

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from -2.5 to 1.5 V vs Ag/Ag+), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials.

Original languageEnglish
Pages (from-to)6057-6059
Number of pages3
JournalTetrahedron Letters
Volume50
Issue number44
DOIs
Publication statusPublished - Nov 4 2009

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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