Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates

Yanying Zhang, Song Tu, Koichi Mitsudo, Hideo Tanaka, Shunzo Suematsu, Kenji Machida, Daisuke Horii, Shuichi Ishimoto, Kenji Tamamitsu

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Novel long-chain dialkyl fluorene-9,9-dicarboxylates were synthesized by treating fluorene with lithium diisopropylamide followed by alkyl chloroformates. The fluorene derivatives were readily electro-oxidized to form electroactive films on the surface of a glassy carbon electrode. From the viewpoint of suitable potential window (from -2.5 to 1.5 V vs Ag/Ag+), cyclic voltammograms of the films indicated the electroactive properties of the fluorene derivatives that make them good candidates for electrochemical capacitor materials.

Original languageEnglish
Pages (from-to)6057-6059
Number of pages3
JournalTetrahedron Letters
Volume50
Issue number44
DOIs
Publication statusPublished - Nov 4 2009

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Polymerization
Derivatives
Glassy carbon
Electrodes
Capacitors
Carbon
fluorene

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Zhang, Y., Tu, S., Mitsudo, K., Tanaka, H., Suematsu, S., Machida, K., ... Tamamitsu, K. (2009). Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates. Tetrahedron Letters, 50(44), 6057-6059. https://doi.org/10.1016/j.tetlet.2009.08.052

Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates. / Zhang, Yanying; Tu, Song; Mitsudo, Koichi; Tanaka, Hideo; Suematsu, Shunzo; Machida, Kenji; Horii, Daisuke; Ishimoto, Shuichi; Tamamitsu, Kenji.

In: Tetrahedron Letters, Vol. 50, No. 44, 04.11.2009, p. 6057-6059.

Research output: Contribution to journalArticle

Zhang, Y, Tu, S, Mitsudo, K, Tanaka, H, Suematsu, S, Machida, K, Horii, D, Ishimoto, S & Tamamitsu, K 2009, 'Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates', Tetrahedron Letters, vol. 50, no. 44, pp. 6057-6059. https://doi.org/10.1016/j.tetlet.2009.08.052
Zhang, Yanying ; Tu, Song ; Mitsudo, Koichi ; Tanaka, Hideo ; Suematsu, Shunzo ; Machida, Kenji ; Horii, Daisuke ; Ishimoto, Shuichi ; Tamamitsu, Kenji. / Synthesis and oxidative polymerization of dialkyl fluorene-9,9-dicarboxylates. In: Tetrahedron Letters. 2009 ; Vol. 50, No. 44. pp. 6057-6059.
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