Synthesis and optical resolution of novel chiral silanols

Atsunori Mori, Fumihiko Toriyama, Hiroshi Kajiro, Kazunori Hirabayashi, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

Silanols bearing an asymmetric center on silicon, methyl(2-phenylethenyl)(3,3,3-trifluoropropyl)silanol and methyl(phenyl)(vinyl)silanol are synthesized by alkylative cleavages of cyclic siloxanes with an organolithium. Optical resolution of their enantiomers is performed by HPLC with a chiral stationary phase column. Optical characters of thus separated enantiomers are also examined.

Original languageEnglish
Pages (from-to)549-550
Number of pages2
JournalChemistry Letters
Issue number7
Publication statusPublished - 1999
Externally publishedYes

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Enantiomers
Bearings (structural)
Siloxanes
Silicon
silanol

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Mori, A., Toriyama, F., Kajiro, H., Hirabayashi, K., Nishihara, Y., & Hiyama, T. (1999). Synthesis and optical resolution of novel chiral silanols. Chemistry Letters, (7), 549-550.

Synthesis and optical resolution of novel chiral silanols. / Mori, Atsunori; Toriyama, Fumihiko; Kajiro, Hiroshi; Hirabayashi, Kazunori; Nishihara, Yasushi; Hiyama, Tamejiro.

In: Chemistry Letters, No. 7, 1999, p. 549-550.

Research output: Contribution to journalArticle

Mori, A, Toriyama, F, Kajiro, H, Hirabayashi, K, Nishihara, Y & Hiyama, T 1999, 'Synthesis and optical resolution of novel chiral silanols', Chemistry Letters, no. 7, pp. 549-550.
Mori A, Toriyama F, Kajiro H, Hirabayashi K, Nishihara Y, Hiyama T. Synthesis and optical resolution of novel chiral silanols. Chemistry Letters. 1999;(7):549-550.
Mori, Atsunori ; Toriyama, Fumihiko ; Kajiro, Hiroshi ; Hirabayashi, Kazunori ; Nishihara, Yasushi ; Hiyama, Tamejiro. / Synthesis and optical resolution of novel chiral silanols. In: Chemistry Letters. 1999 ; No. 7. pp. 549-550.
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