Synthesis and optical resolution of novel chiral silanols

Atsunori Mori, Fumihiko Toriyama, Hiroshi Kajiro, Kazunori Hirabayashi, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

Silanols bearing an asymmetric center on silicon, methyl(2-phenylethenyl)(3,3,3-trifluoropropyl)silanol and methyl(phenyl)(vinyl)silanol are synthesized by alkylative cleavages of cyclic siloxanes with an organolithium. Optical resolution of their enantiomers is performed by HPLC with a chiral stationary phase column. Optical characters of thus separated enantiomers are also examined.

Original languageEnglish
Pages (from-to)549-550
Number of pages2
JournalChemistry Letters
Issue number7
DOIs
Publication statusPublished - 1999
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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