Abstract
Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.
| Original language | English |
|---|---|
| Pages (from-to) | 843-848 |
| Number of pages | 6 |
| Journal | Polyhedron |
| Volume | 21 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Apr 15 2002 |
| Externally published | Yes |
Fingerprint
Keywords
- Benzyl 8-quinolyl sulfide
- Crystal structures
- Palladium(II) complexes
- Phenethyl 8-quinolyl
ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide. / Kita, Masakazu; Abiko, Shin Ichi; Fuyuhiro, Akira; Yamanari, Kazuaki; Murata, Katsuo; Yamashita, Shinsuke.
In: Polyhedron, Vol. 21, No. 8, 15.04.2002, p. 843-848.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide
AU - Kita, Masakazu
AU - Abiko, Shin Ichi
AU - Fuyuhiro, Akira
AU - Yamanari, Kazuaki
AU - Murata, Katsuo
AU - Yamashita, Shinsuke
PY - 2002/4/15
Y1 - 2002/4/15
N2 - Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.
AB - Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.
KW - Benzyl 8-quinolyl sulfide
KW - Crystal structures
KW - Palladium(II) complexes
KW - Phenethyl 8-quinolyl
UR - http://www.scopus.com/inward/record.url?scp=0037090443&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037090443&partnerID=8YFLogxK
U2 - 10.1016/S0277-5387(02)00864-1
DO - 10.1016/S0277-5387(02)00864-1
M3 - Article
AN - SCOPUS:0037090443
VL - 21
SP - 843
EP - 848
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 8
ER -