Abstract
Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.
| Original language | English |
|---|---|
| Pages (from-to) | 843-848 |
| Number of pages | 6 |
| Journal | Polyhedron |
| Volume | 21 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - Apr 15 2002 |
| Externally published | Yes |
Keywords
- Benzyl 8-quinolyl sulfide
- Crystal structures
- Palladium(II) complexes
- Phenethyl 8-quinolyl
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
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Cite this
Kita, M., Abiko, S. I., Fuyuhiro, A., Yamanari, K., Murata, K., & Yamashita, S. (2002). Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide. Polyhedron, 21(8), 843-848. https://doi.org/10.1016/S0277-5387(02)00864-1