Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide

Masakazu Kita; Shin Ichi Abiko; Akira Fuyuhiro; Kazuaki Yamanari; Katsuo Murata; Shinsuke Yamashita

doi:10.1016/S0277-5387(02)00864-1

Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide

Masakazu Kita, Shin Ichi Abiko, Akira Fuyuhiro, Kazuaki Yamanari, Katsuo Murata, Shinsuke Yamashita

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Four palladium(II) complexes [PdX₂(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl₂(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me₂SO, MeCN and MeNO₂. On the other hand, [PdCl₂(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.

Original language	English
Pages (from-to)	843-848
Number of pages	6
Journal	Polyhedron
Volume	21
Issue number	8
DOIs	https://doi.org/10.1016/S0277-5387(02)00864-1
Publication status	Published - Apr 15 2002
Externally published	Yes

Keywords

Benzyl 8-quinolyl sulfide
Crystal structures
Palladium(II) complexes
Phenethyl 8-quinolyl

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{a894bda4f99947b79ff1abe379a3e5a9,

title = "Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide",

abstract = "Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.",

keywords = "Benzyl 8-quinolyl sulfide, Crystal structures, Palladium(II) complexes, Phenethyl 8-quinolyl",

author = "Masakazu Kita and Abiko, {Shin Ichi} and Akira Fuyuhiro and Kazuaki Yamanari and Katsuo Murata and Shinsuke Yamashita",

year = "2002",

month = apr,

day = "15",

doi = "10.1016/S0277-5387(02)00864-1",

language = "English",

volume = "21",

pages = "843--848",

journal = "Polyhedron",

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number = "8",

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TY - JOUR

T1 - Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide

AU - Kita, Masakazu

AU - Abiko, Shin Ichi

AU - Fuyuhiro, Akira

AU - Yamanari, Kazuaki

AU - Murata, Katsuo

AU - Yamashita, Shinsuke

PY - 2002/4/15

Y1 - 2002/4/15

N2 - Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.

AB - Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.

KW - Benzyl 8-quinolyl sulfide

KW - Crystal structures

KW - Palladium(II) complexes

KW - Phenethyl 8-quinolyl

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U2 - 10.1016/S0277-5387(02)00864-1

DO - 10.1016/S0277-5387(02)00864-1

M3 - Article

AN - SCOPUS:0037090443

VL - 21

SP - 843

EP - 848

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 8

ER -

Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide

Abstract

Keywords

ASJC Scopus subject areas

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