Synthesis and crystal structures of palladium(II) complexes containing benzyl 8-quinolyl sulfide and phenethyl 8-quinolyl sulfide

Masakazu Kita, Shin Ichi Abiko, Akira Fuyuhiro, Kazuaki Yamanari, Katsuo Murata, Shinsuke Yamashita

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Four palladium(II) complexes [PdX2(L-N,S)] (X = Cl, Br; L: BzSq = benzyl 8-quinolyl sulfide, PheneSq = phenethyl 8-quinolyl sulfide) were prepared. The crystal structure of [PdCl2(BzSq-N,S)] revealed the presence of an intraligand stacking between the phenyl and quinolyl groups of BzSq. This stacking interaction was confirmed even in Me2SO, MeCN and MeNO2. On the other hand, [PdCl2(PheneSq-N,S)] did not show such an intraligand stacking both in the solid and in solutions.

Original languageEnglish
Pages (from-to)843-848
Number of pages6
JournalPolyhedron
Volume21
Issue number8
DOIs
Publication statusPublished - Apr 15 2002
Externally publishedYes

Keywords

  • Benzyl 8-quinolyl sulfide
  • Crystal structures
  • Palladium(II) complexes
  • Phenethyl 8-quinolyl

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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