Synthesis and crystal structure of a [70] fullerene-pentacene monoadduct

Hitoshi Shirai, Tomoyuki Tajima, Kentaro Kubo, Takuya Nishihama, Hideaki Miyake, Yutaka Takaguchi

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

We succeeded in the first isolation of a single pure regioisomer of a C70-acene monoadduct. 1,9-Diels-Alder monoadducts of C70 with pentacene derivatives were obtained by not only the Diels-Alder reaction but also a one-pot reaction using stable dihydropentacene derivatives, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), and C70. The X-ray crystallographic study of a single pure regioisomer 2b confirmed positions of the linkage between C70 and acenes for the first time, and revealed unique columnar stacks.

Original languageEnglish
Pages (from-to)437-443
Number of pages7
JournalBulletin of the Chemical Society of Japan
Volume89
Issue number4
DOIs
Publication statusPublished - 2016

ASJC Scopus subject areas

  • Chemistry(all)

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