Synthesis and crystal structure of a [70] fullerene-pentacene monoadduct

Hitoshi Shirai, Tomoyuki Tajima, Kentaro Kubo, Takuya Nishihama, Hideaki Miyake, Yutaka Takaguchi

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

We succeeded in the first isolation of a single pure regioisomer of a C70-acene monoadduct. 1,9-Diels-Alder monoadducts of C70 with pentacene derivatives were obtained by not only the Diels-Alder reaction but also a one-pot reaction using stable dihydropentacene derivatives, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), and C70. The X-ray crystallographic study of a single pure regioisomer 2b confirmed positions of the linkage between C70 and acenes for the first time, and revealed unique columnar stacks.

Original languageEnglish
Pages (from-to)437-443
Number of pages7
JournalBulletin of the Chemical Society of Japan
Volume89
Issue number4
DOIs
Publication statusPublished - 2016

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Crystal structure
Derivatives
X rays
pentacene
fullerene C70
dichlorodicyanobenzoquinone

ASJC Scopus subject areas

  • Chemistry(all)

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Synthesis and crystal structure of a [70] fullerene-pentacene monoadduct. / Shirai, Hitoshi; Tajima, Tomoyuki; Kubo, Kentaro; Nishihama, Takuya; Miyake, Hideaki; Takaguchi, Yutaka.

In: Bulletin of the Chemical Society of Japan, Vol. 89, No. 4, 2016, p. 437-443.

Research output: Contribution to journalArticle

Shirai, Hitoshi ; Tajima, Tomoyuki ; Kubo, Kentaro ; Nishihama, Takuya ; Miyake, Hideaki ; Takaguchi, Yutaka. / Synthesis and crystal structure of a [70] fullerene-pentacene monoadduct. In: Bulletin of the Chemical Society of Japan. 2016 ; Vol. 89, No. 4. pp. 437-443.
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