Synthesis and characterization of the first stable stannanetelone

Norihiro Tokitoh, Tomoyuki Tajima, Nobuhiro Takeda, Takahiro Sasamori

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The first example of a stable stannanetellone was synthesized and isolated by taking advantage of kinetic stabilization afforded by the combination of steric protecting groups, 2,6-bis[bis(trimethylsilyl)methyl]-4- [tris(trimethylsilyl)methyl]phenyl (Bbt) and 2,2'',4,4''-tetraisopropyl-m- terphenyl-2'-yl groups. The structural parameters and spectroscopic data of the isolated stannanetellone were systematically compared with those previously reported for the lighter congeners, i. e., the stannanethione and stannaneselone. Attempted synthesis of a stannanetellone by the reaction of dilithiostannane with tellurium dichloride is also described.

Original languageEnglish
Pages (from-to)948-955
Number of pages8
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume183
Issue number4
DOIs
Publication statusPublished - Apr 1 2008
Externally publishedYes

Keywords

  • Dilithiostannane
  • Kinetic stabilization
  • Stannanesellone
  • Stannanetellone
  • Stannanethione
  • Steric protection

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Synthesis and characterization of the first stable stannanetelone'. Together they form a unique fingerprint.

  • Cite this