Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes

Kyosuke Satake, Isao Umemoto, Kunihiro Usumoto, Masaru Kimura, Shiro Morosawa, Tsutomu Kumagai, Toshio Mukai

Research output: Contribution to journalArticle

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Abstract

[8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.

Original languageEnglish
Pages (from-to)163-172
Number of pages10
JournalHeterocycles
Volume31
Issue number1
Publication statusPublished - Jan 1 1990

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Azepines
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ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Satake, K., Umemoto, I., Usumoto, K., Kimura, M., Morosawa, S., Kumagai, T., & Mukai, T. (1990). Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes. Heterocycles, 31(1), 163-172.

Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes. / Satake, Kyosuke; Umemoto, Isao; Usumoto, Kunihiro; Kimura, Masaru; Morosawa, Shiro; Kumagai, Tsutomu; Mukai, Toshio.

In: Heterocycles, Vol. 31, No. 1, 01.01.1990, p. 163-172.

Research output: Contribution to journalArticle

Satake, K, Umemoto, I, Usumoto, K, Kimura, M, Morosawa, S, Kumagai, T & Mukai, T 1990, 'Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes', Heterocycles, vol. 31, no. 1, pp. 163-172.
Satake K, Umemoto I, Usumoto K, Kimura M, Morosawa S, Kumagai T et al. Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes. Heterocycles. 1990 Jan 1;31(1):163-172.
Satake, Kyosuke ; Umemoto, Isao ; Usumoto, Kunihiro ; Kimura, Masaru ; Morosawa, Shiro ; Kumagai, Tsutomu ; Mukai, Toshio. / Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes. In: Heterocycles. 1990 ; Vol. 31, No. 1. pp. 163-172.
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