Abstract
[8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.
| Original language | English |
|---|---|
| Pages (from-to) | 163-172 |
| Number of pages | 10 |
| Journal | Heterocycles |
| Volume | 31 |
| Issue number | 1 |
| Publication status | Published - Jan 1 1990 |
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ASJC Scopus subject areas
- Organic Chemistry
Cite this
Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes. / Satake, Kyosuke; Umemoto, Isao; Usumoto, Kunihiro; Kimura, Masaru; Morosawa, Shiro; Kumagai, Tsutomu; Mukai, Toshio.
In: Heterocycles, Vol. 31, No. 1, 01.01.1990, p. 163-172.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes
AU - Satake, Kyosuke
AU - Umemoto, Isao
AU - Usumoto, Kunihiro
AU - Kimura, Masaru
AU - Morosawa, Shiro
AU - Kumagai, Tsutomu
AU - Mukai, Toshio
PY - 1990/1/1
Y1 - 1990/1/1
N2 - [8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.
AB - [8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.
UR - http://www.scopus.com/inward/record.url?scp=14544297592&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=14544297592&partnerID=8YFLogxK
M3 - Article
VL - 31
SP - 163
EP - 172
JO - Heterocycles
JF - Heterocycles
SN - 0385-5414
IS - 1
ER -