Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes

Kyosuke Satake, Isao Umemoto, Kunihiro Usumoto, Masaru Kimura, Shiro Morosawa, Tsutomu Kumagai, Toshio Mukai

    Research output: Contribution to journalArticlepeer-review

    2 Citations (Scopus)

    Abstract

    [8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.

    Original languageEnglish
    Pages (from-to)163-172
    Number of pages10
    JournalHeterocycles
    Volume31
    Issue number1
    DOIs
    Publication statusPublished - Jan 1 1990

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Pharmacology
    • Organic Chemistry

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