Syntheses and odor descriptions of cyclopropanated compounds part 5. Analogs of methyl jasmonate to fix the relative configuration of the two side chains

Hiromasa Kiyota, Shin Ya Takigawa, Shigefumi Kuwahara

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Analogs of methyl jasmonate (=methyl (1R*,2R*)-3-oxo-2-[(Z)- pent-2-enyl]cyclopentaneacetate; MJA) bearing a cyclopropane ring, double bond, or a F-substituent were synthesized, and their odor characteristics were examined. Most of the analogs with the same stereochemical properties as methyl epijasmonate showed odor properties superior to MJA. Interestingly, the enol acetate of MJA had a diffusive orchid-like note.

Original languageEnglish
Pages (from-to)1854-1859
Number of pages6
JournalHelvetica Chimica Acta
Volume87
Issue number7
DOIs
Publication statusPublished - 2004
Externally publishedYes

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odors
Odors
fixing
Bearings (structural)
analogs
cyclopropane
synthesis
configurations
acetates
Acetates
rings
methyl jasmonate
Odorants

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Syntheses and odor descriptions of cyclopropanated compounds part 5. Analogs of methyl jasmonate to fix the relative configuration of the two side chains. / Kiyota, Hiromasa; Takigawa, Shin Ya; Kuwahara, Shigefumi.

In: Helvetica Chimica Acta, Vol. 87, No. 7, 2004, p. 1854-1859.

Research output: Contribution to journalArticle

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