Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)2]BF4 and dimeric [Cu2(2,3,2-SPPS)2](BF4)2

Kyoko Noda; Tetsuya Sasaki; Satoshi Iwatsuki; Kazuo Kashiwabara; Takayoshi Suzuki; Hideo D. Takagi

doi:10.1016/j.ica.2003.08.008

Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)₂]BF₄ and dimeric [Cu₂(2,3,2-SPPS)₂](BF₄)₂

Kyoko Noda, Tetsuya Sasaki, Satoshi Iwatsuki, Kazuo Kashiwabara, Takayoshi Suzuki, Hideo D. Takagi

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Mononuclear and binuclear complexes of Cu(I) with bidentate and quadridentate phosphine-thioether hybrid ligands were successfully isolated for the first time by mixing aqueous copper(II) with each corresponding ligand: the structures of these complexes were analyzed by the X-ray crystallographic method and the synthetic route for these complexes was clarified on the basis of the electrochemical behaviors of these complexes in solution.

Original language	English
Pages (from-to)	526-532
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	357
Issue number	2
DOIs	https://doi.org/10.1016/j.ica.2003.08.008
Publication status	Published - Jan 30 2004
Externally published	Yes

Keywords

Copper(I) complex
Crystal structure
Electrochemistry
Phosphine-thioether ligand

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ica.2003.08.008

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Noda, K., Sasaki, T., Iwatsuki, S., Kashiwabara, K., Suzuki, T., & Takagi, H. D. (2004). Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)₂]BF₄ and dimeric [Cu₂(2,3,2-SPPS)₂](BF₄)₂. Inorganica Chimica Acta, 357(2), 526-532. https://doi.org/10.1016/j.ica.2003.08.008

Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS) : Successful synthetic route for monomeric [Cu(mtdpp)₂]BF₄ and dimeric [Cu₂(2,3,2-SPPS)₂](BF₄)₂. / Noda, Kyoko; Sasaki, Tetsuya; Iwatsuki, Satoshi et al.

In: Inorganica Chimica Acta, Vol. 357, No. 2, 30.01.2004, p. 526-532.

Research output: Contribution to journal › Article › peer-review

Noda, K, Sasaki, T, Iwatsuki, S, Kashiwabara, K, Suzuki, T & Takagi, HD 2004, 'Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)₂]BF₄ and dimeric [Cu₂(2,3,2-SPPS)₂](BF₄)₂', Inorganica Chimica Acta, vol. 357, no. 2, pp. 526-532. https://doi.org/10.1016/j.ica.2003.08.008

Noda K, Sasaki T, Iwatsuki S, Kashiwabara K, Suzuki T, Takagi HD. Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)₂]BF₄ and dimeric [Cu₂(2,3,2-SPPS)₂](BF₄)₂. Inorganica Chimica Acta. 2004 Jan 30;357(2):526-532. doi: 10.1016/j.ica.2003.08.008

Noda, Kyoko ; Sasaki, Tetsuya ; Iwatsuki, Satoshi et al. / Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS) : Successful synthetic route for monomeric [Cu(mtdpp)₂]BF₄ and dimeric [Cu₂(2,3,2-SPPS)₂](BF₄)₂. In: Inorganica Chimica Acta. 2004 ; Vol. 357, No. 2. pp. 526-532.

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abstract = "Mononuclear and binuclear complexes of Cu(I) with bidentate and quadridentate phosphine-thioether hybrid ligands were successfully isolated for the first time by mixing aqueous copper(II) with each corresponding ligand: the structures of these complexes were analyzed by the X-ray crystallographic method and the synthetic route for these complexes was clarified on the basis of the electrochemical behaviors of these complexes in solution.",

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