Syntheses and first structural analyses of Cu(I)-PS complexes with bidentate 1,1-diphenyl-1-phospha-4-thiapentane (mtdpp) and quadridentate 5,9-diphenyl-5,9-diphospha-2,12-dithiatridecane (2,3,2-SPPS): Successful synthetic route for monomeric [Cu(mtdpp)2]BF4 and dimeric [Cu2(2,3,2-SPPS)2](BF4)2

Kyoko Noda, Tetsuya Sasaki, Satoshi Iwatsuki, Kazuo Kashiwabara, Takayoshi Suzuki, Hideo D. Takagi

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Mononuclear and binuclear complexes of Cu(I) with bidentate and quadridentate phosphine-thioether hybrid ligands were successfully isolated for the first time by mixing aqueous copper(II) with each corresponding ligand: the structures of these complexes were analyzed by the X-ray crystallographic method and the synthetic route for these complexes was clarified on the basis of the electrochemical behaviors of these complexes in solution.

Original languageEnglish
Pages (from-to)526-532
Number of pages7
JournalInorganica Chimica Acta
Volume357
Issue number2
DOIs
Publication statusPublished - Jan 30 2004
Externally publishedYes

Keywords

  • Copper(I) complex
  • Crystal structure
  • Electrochemistry
  • Phosphine-thioether ligand

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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