Surface modification of carbon nanohorns by helium plasma and ozone treatments

Zaw Lin, Toru Iijima, Paneer Selvam Karthik, Mitsunobu Yoshida, Masaki Hada, Takeshi Nishikawa, Yasuhiko Hayashi

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In this paper, we describe the effects of helium plasma and ozone treatments on the dispersibility of carbon nanohorns (CNHs) in water. The experimental setups have been designed to efficiently generate helium plasma and ozone by dielectric barrier discharge at atmospheric pressure. After being treated with ozone, the oxygen-containing functional groups were introduced to the surface of CNHs, and are responsible for better dispersion. Helium plasma treatment was performed separately and it resulted in hydroxyl functional groups on the surface of CNHs. It was also found that the sizes of CNHs in water were smaller after ozone treatment. However, plasma-treated CNHs were bigger than ozone treated CNHs. The dispersed CNHs modified by ozone treatment were stable for more than three months without precipitation. In contrast, though helium plasma treatment introduced hydroxyl groups to the surface of CNHs, the dispersibility decreased and the flocculation of CNHs was observed in a few minutes.

Original languageEnglish
Article number01AB08
JournalJapanese Journal of Applied Physics
Volume56
Issue number1
DOIs
Publication statusPublished - Jan 1 2017

Fingerprint

Nanohorns
helium plasma
Ozone
ozone
Helium
Surface treatment
Plasmas
Carbon
carbon
Functional groups
Flocculation
water
Atmospheric pressure
Water
atmospheric pressure

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Surface modification of carbon nanohorns by helium plasma and ozone treatments. / Lin, Zaw; Iijima, Toru; Karthik, Paneer Selvam; Yoshida, Mitsunobu; Hada, Masaki; Nishikawa, Takeshi; Hayashi, Yasuhiko.

In: Japanese Journal of Applied Physics, Vol. 56, No. 1, 01AB08, 01.01.2017.

Research output: Contribution to journalArticle

Lin, Zaw ; Iijima, Toru ; Karthik, Paneer Selvam ; Yoshida, Mitsunobu ; Hada, Masaki ; Nishikawa, Takeshi ; Hayashi, Yasuhiko. / Surface modification of carbon nanohorns by helium plasma and ozone treatments. In: Japanese Journal of Applied Physics. 2017 ; Vol. 56, No. 1.
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